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@ARTICLE{Jeangros:825440,
author = {Jeangros, Quentin and Duchamp, Martial and Werner, Jonas
and Kruth, Maximilian and Dunin-Borkowski, Rafal and Niesen,
B. and Ballif, C. and Hessler - Wyser, A.},
title = {{I}n situ {TEM} {A}nalysis of organic-inorganic
metal-halide perovskite solar cells under electrical bias},
journal = {Nano letters},
volume = {11},
issn = {1530-6984},
address = {Washington, DC},
publisher = {ACS Publ.},
reportid = {FZJ-2016-07903},
pages = {7013},
year = {2016},
abstract = {Changes in the nanostructure of methylammonium lead iodide
(MAPbI3) perovskite solar cells are assessed as a function
of current–voltage stimulus by biasing thin samples in
situ in a transmission electron microscope. Various
degradation pathways are identified both in situ and ex
situ, predominantly at the positively biased MAPbI3
interface. Iodide migrates into the positively biased charge
transport layer and also volatilizes along with organic
species, which triggers the nucleation of PbI2 nanoparticles
and voids and hence decreases the cell performance.},
cin = {PGI-5},
ddc = {540},
cid = {I:(DE-Juel1)PGI-5-20110106},
pnm = {143 - Controlling Configuration-Based Phenomena (POF3-143)},
pid = {G:(DE-HGF)POF3-143},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000387625000044},
pubmed = {pmid:27775887},
doi = {10.1021/acs.nanolett.6b03158},
url = {https://juser.fz-juelich.de/record/825440},
}