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@ARTICLE{Xi:825451,
      author       = {Xi, Lifei and Cho, Deok-Yong and Besmehn, Astrid and
                      Duchamp, Martial and Grützmacher, Detlev and Lam, Yeng Ming
                      and Kardynał, Beata E.},
      title        = {{E}ffect of {Z}inc {I}ncorporation on the {P}erformance of
                      {R}ed {L}ight {E}mitting {I}n{P} {C}ore {N}anocrystals},
      journal      = {Inorganic chemistry},
      volume       = {55},
      number       = {17},
      issn         = {1520-510X},
      address      = {Washington, DC},
      publisher    = {American Chemical Society},
      reportid     = {FZJ-2016-07914},
      pages        = {8381 - 8386},
      year         = {2016},
      abstract     = {This report presents a systematic study on the effect of
                      zinc (Zn) carboxylate precursor on the structural and
                      optical properties of red light emitting InP nanocrystals
                      (NCs). NC cores were assessed using X-ray photoelectron
                      spectroscopy (XPS), X-ray absorption spectroscopy (XAS),
                      energy-dispersive X-ray spectroscopy (EDX), and
                      high-resolution transmission electron microscopy (HRTEM).
                      When moderate Zn:In ratios in the reaction pot were used,
                      the incorporation of Zn in InP was insufficient to change
                      the crystal structure or band gap of the NCs, but
                      photoluminescence quantum yield (PLQY) increased
                      dramatically compared with pure InP NCs. Zn was found to
                      incorporate mostly in the phosphate layer on the NCs. PL,
                      PLQY, and time-resolved PL (TRPL) show that Zn carboxylates
                      added to the precursors during NC cores facilitate the
                      synthesis of high-quality InP NCs by suppressing
                      nonradiative and sub-band-gap recombination, and the effect
                      is visible also after a ZnS shell is grown on the cores.},
      cin          = {PGI-5 / PGI-9 / JARA-FIT / ZEA-3},
      ddc          = {540},
      cid          = {I:(DE-Juel1)PGI-5-20110106 / I:(DE-Juel1)PGI-9-20110106 /
                      $I:(DE-82)080009_20140620$ / I:(DE-Juel1)ZEA-3-20090406},
      pnm          = {143 - Controlling Configuration-Based Phenomena (POF3-143)},
      pid          = {G:(DE-HGF)POF3-143},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000382713900024},
      pubmed       = {pmid:27551948},
      doi          = {10.1021/acs.inorgchem.6b00747},
      url          = {https://juser.fz-juelich.de/record/825451},
}