000825695 001__ 825695
000825695 005__ 20240619092046.0
000825695 0247_ $$2doi$$a10.1039/C6CP06964A
000825695 0247_ $$2ISSN$$a1463-9076
000825695 0247_ $$2ISSN$$a1463-9084
000825695 0247_ $$2WOS$$aWOS:000391725300081
000825695 0247_ $$2altmetric$$aaltmetric:14949655
000825695 0247_ $$2pmid$$apmid:27929164
000825695 037__ $$aFZJ-2017-00012
000825695 041__ $$aEnglish
000825695 082__ $$a540
000825695 1001_ $$0P:(DE-HGF)0$$aGaudino, D.$$b0$$eCorresponding author
000825695 245__ $$aThe role of the binding salt sodium salicylate in semidilute ionic cetylpyridinium chloride micellar solutions: a rheological and scattering study
000825695 260__ $$aCambridge$$bRSC Publ.$$c2017
000825695 3367_ $$2DRIVER$$aarticle
000825695 3367_ $$2DataCite$$aOutput Types/Journal article
000825695 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1522227543_32427
000825695 3367_ $$2BibTeX$$aARTICLE
000825695 3367_ $$2ORCID$$aJOURNAL_ARTICLE
000825695 3367_ $$00$$2EndNote$$aJournal Article
000825695 520__ $$aThe micellar system based on cetylpyridinium chloride (CPyCl) and sodium salicylate (NaSal) in brine solution is investigated on both macro- and micro-length scales through rheology and scattering measurements. The linear viscoelasticity of the system and its structural parameters are explored by systematically changing the amount of NaSal over an extremely wide range of concentrations, thus producing salt-to-surfactant molar ratios from zero to about 8.5. As a result, the well-known non-monotonic behaviour of the zero-shear rate viscosity as a function of salinity can be connected to micellar morphological changes, whose driving force is represented by the simultaneous binding and screening actions of NaSal. The viscosity behaviour can be seen as a direct consequence of consecutive lengthening/shortening of the contour length, where the micelles attempt to minimize the electrostatic charge density on their surface. Along similar lines, the scattering measurements of the semidilute solutions show that the local stiffness of the micellar chain changes with increasing salt content influencing the elasticity of the resulting network. Within this general view, the branching of the micelles can be seen as a side effect attributable to the main character of the play, namely, the binding salt NaSal, whereas the overall dynamics of the system is driven by the considerable changes in the entanglement density of the micellar network.
000825695 536__ $$0G:(DE-HGF)POF3-551$$a551 - Functional Macromolecules and Complexes (POF3-551)$$cPOF3-551$$fPOF III$$x0
000825695 536__ $$0G:(DE-HGF)POF3-6G4$$a6G4 - Jülich Centre for Neutron Research (JCNS) (POF3-623)$$cPOF3-623$$fPOF III$$x1
000825695 536__ $$0G:(DE-HGF)POF3-6215$$a6215 - Soft Matter, Health and Life Sciences (POF3-621)$$cPOF3-621$$fPOF III$$x2
000825695 588__ $$aDataset connected to CrossRef
000825695 65027 $$0V:(DE-MLZ)SciArea-210$$2V:(DE-HGF)$$aSoft Condensed Matter$$x0
000825695 65017 $$0V:(DE-MLZ)GC-1603-2016$$2V:(DE-HGF)$$aChemical Reactions and Advanced Materials$$x0
000825695 693__ $$0EXP:(DE-MLZ)KWS2-20140101$$1EXP:(DE-MLZ)FRMII-20140101$$5EXP:(DE-MLZ)KWS2-20140101$$6EXP:(DE-MLZ)NL3ao-20140101$$aForschungs-Neutronenquelle Heinz Maier-Leibnitz $$eKWS-2: Small angle scattering diffractometer$$fNL3ao$$x0
000825695 693__ $$0EXP:(DE-MLZ)KWS3-20140101$$1EXP:(DE-MLZ)FRMII-20140101$$5EXP:(DE-MLZ)KWS3-20140101$$6EXP:(DE-MLZ)NL3auS-20140101$$aForschungs-Neutronenquelle Heinz Maier-Leibnitz $$eKWS-3: Very small angle scattering diffractometer with focusing mirror$$fNL3auS$$x1
000825695 7001_ $$0P:(DE-HGF)0$$aPasquino, R.$$b1
000825695 7001_ $$0P:(DE-Juel1)130986$$aStellbrink, J.$$b2$$ufzj
000825695 7001_ $$0P:(DE-Juel1)145431$$aSzekely, N.$$b3$$ufzj
000825695 7001_ $$0P:(DE-Juel1)130777$$aKrutyeva, M.$$b4$$ufzj
000825695 7001_ $$0P:(DE-Juel1)130905$$aRadulescu, A.$$b5$$ufzj
000825695 7001_ $$0P:(DE-Juel1)130902$$aPyckhout-Hintzen, W.$$b6$$ufzj
000825695 7001_ $$0P:(DE-HGF)0$$aGrizzuti, N.$$b7
000825695 773__ $$0PERI:(DE-600)1476244-4$$a10.1039/C6CP06964A$$gVol. 19, no. 1, p. 782 - 790$$n1$$p782 - 790$$tPhysical chemistry, chemical physics$$v19$$x1463-9084$$y2017
000825695 8564_ $$uhttps://juser.fz-juelich.de/record/825695/files/c6cp06964a.pdf$$yRestricted
000825695 8564_ $$uhttps://juser.fz-juelich.de/record/825695/files/c6cp06964a.gif?subformat=icon$$xicon$$yRestricted
000825695 8564_ $$uhttps://juser.fz-juelich.de/record/825695/files/c6cp06964a.jpg?subformat=icon-1440$$xicon-1440$$yRestricted
000825695 8564_ $$uhttps://juser.fz-juelich.de/record/825695/files/c6cp06964a.jpg?subformat=icon-180$$xicon-180$$yRestricted
000825695 8564_ $$uhttps://juser.fz-juelich.de/record/825695/files/c6cp06964a.jpg?subformat=icon-640$$xicon-640$$yRestricted
000825695 8564_ $$uhttps://juser.fz-juelich.de/record/825695/files/c6cp06964a.pdf?subformat=pdfa$$xpdfa$$yRestricted
000825695 909CO $$ooai:juser.fz-juelich.de:825695$$pVDB$$pVDB:MLZ
000825695 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)130986$$aForschungszentrum Jülich$$b2$$kFZJ
000825695 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)145431$$aForschungszentrum Jülich$$b3$$kFZJ
000825695 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)130777$$aForschungszentrum Jülich$$b4$$kFZJ
000825695 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)130905$$aForschungszentrum Jülich$$b5$$kFZJ
000825695 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)130902$$aForschungszentrum Jülich$$b6$$kFZJ
000825695 9131_ $$0G:(DE-HGF)POF3-551$$1G:(DE-HGF)POF3-550$$2G:(DE-HGF)POF3-500$$3G:(DE-HGF)POF3$$4G:(DE-HGF)POF$$aDE-HGF$$bKey Technologies$$lBioSoft – Fundamentals for future Technologies in the fields of Soft Matter and Life Sciences$$vFunctional Macromolecules and Complexes$$x0
000825695 9131_ $$0G:(DE-HGF)POF3-623$$1G:(DE-HGF)POF3-620$$2G:(DE-HGF)POF3-600$$3G:(DE-HGF)POF3$$4G:(DE-HGF)POF$$9G:(DE-HGF)POF3-6G4$$aDE-HGF$$bForschungsbereich Materie$$lVon Materie zu Materialien und Leben$$vFacility topic: Neutrons for Research on Condensed Matter$$x1
000825695 9131_ $$0G:(DE-HGF)POF3-621$$1G:(DE-HGF)POF3-620$$2G:(DE-HGF)POF3-600$$3G:(DE-HGF)POF3$$4G:(DE-HGF)POF$$9G:(DE-HGF)POF3-6215$$aDE-HGF$$bForschungsbereich Materie$$lVon Materie zu Materialien und Leben$$vIn-house research on the structure, dynamics and function of matter$$x2
000825695 9141_ $$y2017
000825695 915__ $$0StatID:(DE-HGF)0400$$2StatID$$aAllianz-Lizenz / DFG
000825695 915__ $$0StatID:(DE-HGF)0420$$2StatID$$aNationallizenz
000825695 915__ $$0StatID:(DE-HGF)0100$$2StatID$$aJCR$$bPHYS CHEM CHEM PHYS : 2015
000825695 915__ $$0StatID:(DE-HGF)0200$$2StatID$$aDBCoverage$$bSCOPUS
000825695 915__ $$0StatID:(DE-HGF)0300$$2StatID$$aDBCoverage$$bMedline
000825695 915__ $$0StatID:(DE-HGF)0310$$2StatID$$aDBCoverage$$bNCBI Molecular Biology Database
000825695 915__ $$0StatID:(DE-HGF)0199$$2StatID$$aDBCoverage$$bThomson Reuters Master Journal List
000825695 915__ $$0StatID:(DE-HGF)0110$$2StatID$$aWoS$$bScience Citation Index
000825695 915__ $$0StatID:(DE-HGF)0150$$2StatID$$aDBCoverage$$bWeb of Science Core Collection
000825695 915__ $$0StatID:(DE-HGF)0111$$2StatID$$aWoS$$bScience Citation Index Expanded
000825695 915__ $$0StatID:(DE-HGF)1150$$2StatID$$aDBCoverage$$bCurrent Contents - Physical, Chemical and Earth Sciences
000825695 915__ $$0StatID:(DE-HGF)9900$$2StatID$$aIF < 5
000825695 9201_ $$0I:(DE-Juel1)ICS-1-20110106$$kICS-1$$lNeutronenstreuung $$x0
000825695 9201_ $$0I:(DE-Juel1)JCNS-1-20110106$$kNeutronenstreuung ; JCNS-1$$lNeutronenstreuung $$x1
000825695 9201_ $$0I:(DE-Juel1)JCNS-FRM-II-20110218$$kJCNS (München) ; Jülich Centre for Neutron Science JCNS (München) ; JCNS-FRM-II$$lJCNS-FRM-II$$x2
000825695 980__ $$ajournal
000825695 980__ $$aVDB
000825695 980__ $$aI:(DE-Juel1)ICS-1-20110106
000825695 980__ $$aI:(DE-Juel1)JCNS-1-20110106
000825695 980__ $$aI:(DE-Juel1)JCNS-FRM-II-20110218
000825695 980__ $$aUNRESTRICTED
000825695 981__ $$aI:(DE-Juel1)IBI-8-20200312
000825695 981__ $$aI:(DE-Juel1)JCNS-1-20110106