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@ARTICLE{Gaudino:825695,
      author       = {Gaudino, D. and Pasquino, R. and Stellbrink, J. and
                      Szekely, N. and Krutyeva, M. and Radulescu, A. and
                      Pyckhout-Hintzen, W. and Grizzuti, N.},
      title        = {{T}he role of the binding salt sodium salicylate in
                      semidilute ionic cetylpyridinium chloride micellar
                      solutions: a rheological and scattering study},
      journal      = {Physical chemistry, chemical physics},
      volume       = {19},
      number       = {1},
      issn         = {1463-9084},
      address      = {Cambridge},
      publisher    = {RSC Publ.},
      reportid     = {FZJ-2017-00012},
      pages        = {782 - 790},
      year         = {2017},
      abstract     = {The micellar system based on cetylpyridinium chloride
                      (CPyCl) and sodium salicylate (NaSal) in brine solution is
                      investigated on both macro- and micro-length scales through
                      rheology and scattering measurements. The linear
                      viscoelasticity of the system and its structural parameters
                      are explored by systematically changing the amount of NaSal
                      over an extremely wide range of concentrations, thus
                      producing salt-to-surfactant molar ratios from zero to about
                      8.5. As a result, the well-known non-monotonic behaviour of
                      the zero-shear rate viscosity as a function of salinity can
                      be connected to micellar morphological changes, whose
                      driving force is represented by the simultaneous binding and
                      screening actions of NaSal. The viscosity behaviour can be
                      seen as a direct consequence of consecutive
                      lengthening/shortening of the contour length, where the
                      micelles attempt to minimize the electrostatic charge
                      density on their surface. Along similar lines, the
                      scattering measurements of the semidilute solutions show
                      that the local stiffness of the micellar chain changes with
                      increasing salt content influencing the elasticity of the
                      resulting network. Within this general view, the branching
                      of the micelles can be seen as a side effect attributable to
                      the main character of the play, namely, the binding salt
                      NaSal, whereas the overall dynamics of the system is driven
                      by the considerable changes in the entanglement density of
                      the micellar network.},
      cin          = {ICS-1 / Neutronenstreuung ; JCNS-1 / JCNS (München) ;
                      Jülich Centre for Neutron Science JCNS (München) ;
                      JCNS-FRM-II},
      ddc          = {540},
      cid          = {I:(DE-Juel1)ICS-1-20110106 / I:(DE-Juel1)JCNS-1-20110106 /
                      I:(DE-Juel1)JCNS-FRM-II-20110218},
      pnm          = {551 - Functional Macromolecules and Complexes (POF3-551) /
                      6G4 - Jülich Centre for Neutron Research (JCNS) (POF3-623)
                      / 6215 - Soft Matter, Health and Life Sciences (POF3-621)},
      pid          = {G:(DE-HGF)POF3-551 / G:(DE-HGF)POF3-6G4 /
                      G:(DE-HGF)POF3-6215},
      experiment   = {EXP:(DE-MLZ)KWS2-20140101 / EXP:(DE-MLZ)KWS3-20140101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000391725300081},
      pubmed       = {pmid:27929164},
      doi          = {10.1039/C6CP06964A},
      url          = {https://juser.fz-juelich.de/record/825695},
}