000825798 001__ 825798 000825798 005__ 20210129225431.0 000825798 0247_ $$2doi$$a10.1021/acs.jpcc.6b00566 000825798 0247_ $$2ISSN$$a1932-7447 000825798 0247_ $$2ISSN$$a1932-7455 000825798 0247_ $$2WOS$$aWOS:000373416500044 000825798 037__ $$aFZJ-2017-00100 000825798 082__ $$a540 000825798 1001_ $$0P:(DE-HGF)0$$aKakudate, Toshiyuki$$b0$$eCorresponding author 000825798 245__ $$aElectronic Structures of Quaterthiophene and Septithiophene on Cu(111): Spatial Distribution of Adsorption-Induced States Studied by STM and DFT Calculation 000825798 260__ $$aWashington, DC$$bSoc.$$c2016 000825798 3367_ $$2DRIVER$$aarticle 000825798 3367_ $$2DataCite$$aOutput Types/Journal article 000825798 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1483610448_4018 000825798 3367_ $$2BibTeX$$aARTICLE 000825798 3367_ $$2ORCID$$aJOURNAL_ARTICLE 000825798 3367_ $$00$$2EndNote$$aJournal Article 000825798 520__ $$aThe oligothiophene molecule family has a tunable energy gap between the highest occupied and lowest unoccupied molecular orbitals (HOMO and LUMO) as the function of the number of thiophene units. This tunability is of great use to controlling carrier injection at the molecule/electrode interface in molecule-based electronic devices. We investigate quaterthiophene (4T) and septithiophene (7T) molecules adsorbed on Cu(111) surfaces by scanning tunneling microscopy and spectroscopy (STM and STS) at room temperature. Both oligothiophene molecules form one-dimensional (1D) chain structures on Cu(111), and each molecule in the 1D structures is observed as a row of bright ovals corresponding to thiophene units. Observed features of 4T and 7T molecules differ from those expected from the HOMO and LUMO of the free-standing molecules, and density-functional calculations of a 4T molecule together with a Cu(111) surface reproduce the experimental STM images as they reflect characteristic spatial distribution of adsorption-induced states. In other words, the adsorption-induced states are spatially protruding out from the molecule and not completely localized in the space between the molecule and the Cu(111) surface. 000825798 536__ $$0G:(DE-HGF)POF3-142$$a142 - Controlling Spin-Based Phenomena (POF3-142)$$cPOF3-142$$fPOF III$$x0 000825798 536__ $$0G:(DE-HGF)POF3-143$$a143 - Controlling Configuration-Based Phenomena (POF3-143)$$cPOF3-143$$fPOF III$$x1 000825798 588__ $$aDataset connected to CrossRef 000825798 7001_ $$0P:(DE-Juel1)131010$$aTsukamoto, Shigeru$$b1 000825798 7001_ $$0P:(DE-HGF)0$$aKubo, Osamu$$b2 000825798 7001_ $$0P:(DE-HGF)0$$aNakaya, Masato$$b3 000825798 7001_ $$0P:(DE-HGF)0$$aNakayama, Tomonobu$$b4 000825798 773__ $$0PERI:(DE-600)2256522-X$$a10.1021/acs.jpcc.6b00566$$gVol. 120, no. 12, p. 6681 - 6688$$n12$$p6681 - 6688$$tThe @journal of physical chemistry <Washington, DC> / C$$v120$$x1932-7455$$y2016 000825798 8564_ $$uhttps://juser.fz-juelich.de/record/825798/files/acs.jpcc.6b00566.pdf$$yRestricted 000825798 8564_ $$uhttps://juser.fz-juelich.de/record/825798/files/acs.jpcc.6b00566.gif?subformat=icon$$xicon$$yRestricted 000825798 8564_ $$uhttps://juser.fz-juelich.de/record/825798/files/acs.jpcc.6b00566.jpg?subformat=icon-1440$$xicon-1440$$yRestricted 000825798 8564_ $$uhttps://juser.fz-juelich.de/record/825798/files/acs.jpcc.6b00566.jpg?subformat=icon-180$$xicon-180$$yRestricted 000825798 8564_ $$uhttps://juser.fz-juelich.de/record/825798/files/acs.jpcc.6b00566.jpg?subformat=icon-640$$xicon-640$$yRestricted 000825798 8564_ $$uhttps://juser.fz-juelich.de/record/825798/files/acs.jpcc.6b00566.pdf?subformat=pdfa$$xpdfa$$yRestricted 000825798 909CO $$ooai:juser.fz-juelich.de:825798$$pVDB 000825798 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)131010$$aForschungszentrum Jülich$$b1$$kFZJ 000825798 9131_ $$0G:(DE-HGF)POF3-142$$1G:(DE-HGF)POF3-140$$2G:(DE-HGF)POF3-100$$3G:(DE-HGF)POF3$$4G:(DE-HGF)POF$$aDE-HGF$$bEnergie$$lFuture Information Technology - Fundamentals, Novel Concepts and Energy Efficiency (FIT)$$vControlling Spin-Based Phenomena$$x0 000825798 9131_ $$0G:(DE-HGF)POF3-143$$1G:(DE-HGF)POF3-140$$2G:(DE-HGF)POF3-100$$3G:(DE-HGF)POF3$$4G:(DE-HGF)POF$$aDE-HGF$$bEnergie$$lFuture Information Technology - Fundamentals, Novel Concepts and Energy Efficiency (FIT)$$vControlling Configuration-Based Phenomena$$x1 000825798 9141_ $$y2016 000825798 915__ $$0StatID:(DE-HGF)0200$$2StatID$$aDBCoverage$$bSCOPUS 000825798 915__ $$0StatID:(DE-HGF)0100$$2StatID$$aJCR$$bJ PHYS CHEM C : 2015 000825798 915__ $$0StatID:(DE-HGF)0150$$2StatID$$aDBCoverage$$bWeb of Science Core Collection 000825798 915__ $$0StatID:(DE-HGF)0110$$2StatID$$aWoS$$bScience Citation Index 000825798 915__ $$0StatID:(DE-HGF)0111$$2StatID$$aWoS$$bScience Citation Index Expanded 000825798 915__ $$0StatID:(DE-HGF)9900$$2StatID$$aIF < 5 000825798 915__ $$0StatID:(DE-HGF)1150$$2StatID$$aDBCoverage$$bCurrent Contents - Physical, Chemical and Earth Sciences 000825798 915__ $$0StatID:(DE-HGF)0300$$2StatID$$aDBCoverage$$bMedline 000825798 915__ $$0StatID:(DE-HGF)0550$$2StatID$$aNo Authors Fulltext 000825798 915__ $$0StatID:(DE-HGF)0199$$2StatID$$aDBCoverage$$bThomson Reuters Master Journal List 000825798 9201_ $$0I:(DE-Juel1)IAS-1-20090406$$kIAS-1$$lQuanten-Theorie der Materialien$$x0 000825798 9201_ $$0I:(DE-Juel1)PGI-1-20110106$$kPGI-1$$lQuanten-Theorie der Materialien$$x1 000825798 9201_ $$0I:(DE-82)080009_20140620$$kJARA-FIT$$lJARA-FIT$$x2 000825798 9201_ $$0I:(DE-82)080012_20140620$$kJARA-HPC$$lJARA - HPC$$x3 000825798 980__ $$ajournal 000825798 980__ $$aVDB 000825798 980__ $$aUNRESTRICTED 000825798 980__ $$aI:(DE-Juel1)IAS-1-20090406 000825798 980__ $$aI:(DE-Juel1)PGI-1-20110106 000825798 980__ $$aI:(DE-82)080009_20140620 000825798 980__ $$aI:(DE-82)080012_20140620