Conference Presentation (Other) FZJ-2017-00259

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Characterization of magnetite nanoparticle / polymer nanocomposite materials in gel and dry state



2016

16th INTERNATIONAL CONFERENCE ON NANOTECHNOLOGY, IEEE NANO 2016, Uni SendaiSendai, Uni Sendai, Japan, 22 Aug 2016 - 25 Aug 20162016-08-222016-08-25

Abstract: We present the characterization of nanocomposite materials made from functionalized magnetite nanoparticles and HEUR amphiphilic polymers in the gel and dry states. The hydrophobically modified particles are mainlyassociated with the two hydrophobic end-groups of the polymer. One part of this study focuses on the polymeric state and dynamics, that are governed by the polymeric network through amphiphilic interactions forming a gel in the wet state and microphase separated system in the dry state. Apart from the network, the particles seem to be well distributed at concentrations below 1%wt, while strong clustering is observed at higher concentrations. The magnetic response of the dry nanocomposite shows super-paramagnetic behavior with a blocking temperature of ca. 25K.

Keyword(s): Polymers, Soft Nano Particles and Proteins (1st) ; Energy (1st) ; Soft Condensed Matter (2nd)


Contributing Institute(s):
  1. JCNS-FRM-II (JCNS (München) ; Jülich Centre for Neutron Science JCNS (München) ; JCNS-FRM-II)
  2. Neutronenstreuung (Neutronenstreuung ; JCNS-1)
Research Program(s):
  1. 144 - Controlling Collective States (POF3-144) (POF3-144)
  2. 6213 - Materials and Processes for Energy and Transport Technologies (POF3-621) (POF3-621)
  3. 6G15 - FRM II / MLZ (POF3-6G15) (POF3-6G15)
  4. 6G4 - Jülich Centre for Neutron Research (JCNS) (POF3-623) (POF3-623)
  5. 6215 - Soft Matter, Health and Life Sciences (POF3-621) (POF3-621)
Experiment(s):
  1. KWS-1: Small angle scattering diffractometer (NL3b)
  2. J-NSE: Neutron spin-echo spectrometer (NL2ao)

Appears in the scientific report 2016
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 Record created 2017-01-10, last modified 2021-01-29


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