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000826001 037__ $$aFZJ-2017-00273
000826001 041__ $$aEnglish
000826001 1001_ $$0P:(DE-Juel1)130646$$aFrielinghaus, Henrich$$b0$$eCorresponding author
000826001 1112_ $$aHelmholtz programme „From Matter to Materials and Life“ - Workshop at DESY$$cHamburg$$d2016-12-14 - 2016-12-16$$gMML2016$$wGermany
000826001 245__ $$aMorphological Changes of Metal Phosphides as Anode Materials in Lithium-Ion Batteries
000826001 260__ $$c2016
000826001 3367_ $$033$$2EndNote$$aConference Paper
000826001 3367_ $$2DataCite$$aOther
000826001 3367_ $$2BibTeX$$aINPROCEEDINGS
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000826001 3367_ $$2ORCID$$aLECTURE_SPEECH
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000826001 502__ $$cDESY
000826001 520__ $$aThe binary metal phosphides (M-P, M= Cu, Fe, Sn, Sb) compounds are of great interest as negative electrode materials for high energy density lithium-ion batteries. However, the morphology and structural changes at the nanoscale upon electrochemical (de)lithiation are not clear yet, which require further detailed investigation. In-situ neutron scattering technique was utilized to investigate and compare the morphological changes of copper phosphide and tin phosphide during the initial cycle. By coupling with SEM investigation, the surface activities of the electrodes at different electrochemical state, including the SEI formation, swelling and recovering, cracks appearance and stripping at nanoscale of the material particles are evaluated. With in-situ XRD measurement, the energy storage mechanism was further explained. This work demonstrates useful techniques to analyze the detailed fatigue mechanisms of the active material, and provides new insights of the nanostructural changes of anode materials reacting with lithium via conversion and alloying.
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000826001 65027 $$0V:(DE-MLZ)SciArea-180$$2V:(DE-HGF)$$aMaterials Science$$x1
000826001 65017 $$0V:(DE-MLZ)GC-1602-2016$$2V:(DE-HGF)$$aPolymers, Soft Nano Particles and  Proteins$$x0
000826001 65017 $$0V:(DE-MLZ)GC-110$$2V:(DE-HGF)$$aEnergy$$x1
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000826001 7001_ $$0P:(DE-Juel1)169319$$aHe, Xin$$b1
000826001 7001_ $$0P:(DE-Juel1)161485$$aWang, Rui$$b2
000826001 7001_ $$0P:(DE-Juel1)166311$$aPaillard, Elie-Elisée$$b3
000826001 7001_ $$0P:(DE-HGF)0$$aMünster, Jie Li WWU$$b4
000826001 8564_ $$uhttp://photon-science.desy.de/news__events/news__highlights/helmholtz_programme_from_matter_to_materials_and_life___workshop_at_desy/index_eng.html
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000826001 9141_ $$y2016
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