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037 _ _ |a FZJ-2017-00375
041 _ _ |a English
100 1 _ |a Lettinga, M.P.
|0 P:(DE-Juel1)130797
|b 0
|e Corresponding author
|u fzj
111 2 _ |a International Conference on Rheology and Fluid Mechanics
|c Alicante
|d 2016-11-10 - 2016-11-11
|w Spain
245 _ _ |a Anomalous response of nematic platelets under LAOStress and strain revealed by 3D Rheo-SAXS
260 _ _ |c 2016
336 7 _ |a Conference Paper
|0 33
|2 EndNote
336 7 _ |a Other
|2 DataCite
336 7 _ |a INPROCEEDINGS
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336 7 _ |a LECTURE_SPEECH
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336 7 _ |a Conference Presentation
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520 _ _ |a Dispersions of colloidal Gibbsite platelets in the nematic phase display a complex response to large amplitude oscillatory shear (LAOS) flow that strongly depends on the strain amplitude. In this work, we applied LAOStress and LAOStrain to the nematic dispersion and probed the structure with time-resolved SAXS measurements. By using plate-plate and couette geometry, we had access to both the flow-vorticity and flow-gradient plane, respectively. Thus we obtained the full 3D rotational motion of the director. For LAOStress, we observed strong asymmetrical behavior both in the rheological and the microscopic response. This asymmetry is connected to the yielding behavior of the platelets. By increasing the stress amplitude we observed that the response becomes more symmetric; however, this strongly depends on the frequency, hence the time necessary for the system to yield. Softening of the response towards the center of the gap was observed by scanning the gap while performing LAOStrain. The structural response at low strain amplitude does not propagate throughout the gap, whereas at high strain amplitudes the response in the bulk emerges as erratic.
536 _ _ |a 551 - Functional Macromolecules and Complexes (POF3-551)
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910 1 _ |a Forschungszentrum Jülich
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913 1 _ |a DE-HGF
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|l BioSoft – Fundamentals for future Technologies in the fields of Soft Matter and Life Sciences
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914 1 _ |y 2016
915 _ _ |a No Authors Fulltext
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920 1 _ |0 I:(DE-Juel1)ICS-3-20110106
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980 _ _ |a conf
980 _ _ |a VDB
980 _ _ |a UNRESTRICTED
980 _ _ |a I:(DE-Juel1)ICS-3-20110106


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