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@ARTICLE{Skiborowski:826304,
author = {Skiborowski, Mirko and Bausa, Jürgen and Marquardt,
Wolfgang},
title = {{A} {U}nifying {A}pproach for the {C}alculation of
{A}zeotropes and {P}inch {P}oints in {H}omogeneous and
{H}eterogeneous {M}ixtures},
journal = {Industrial $\&$ engineering chemistry},
volume = {55},
number = {24},
issn = {1520-5045},
address = {Washington, DC},
publisher = {Soc.75198},
reportid = {FZJ-2017-00537},
pages = {6815 - 6834},
year = {2016},
abstract = {This paper presents a unifying approach for a reliable
calculation of all azeotropes and pinch points for
homogeneous and heterogeneous non-reactive mixtures. The
approach builds on a reformulation of the pinch-equation
system and an efficient continuation algorithm including
bifurcation analysis. The calculation of azeotropes is based
on an analogy of univolatility curves and the pinch branches
for pure component products. The resulting method can
efficiently and reliably calculate all homogeneous and
heterogeneous non-reactive azeotropes. The only exception
would be the existence of isolated univolatility curves
inside the composition space, which to the best knowledge of
the authors has never been reported. Since the method can
further determine the pinch branches and pinch points based
on the knowledge of the azeotropes, it presents a
self-contained method for calculation of the most important
information on nonideal multicomponent mixtures to support
process synthesis. The application of the method is
illustrated by means of several complex mixtures.},
cin = {VS-V},
ddc = {540},
cid = {I:(DE-Juel1)VS-V-20090406},
pnm = {899 - ohne Topic (POF3-899)},
pid = {G:(DE-HGF)POF3-899},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000378583900009},
doi = {10.1021/acs.iecr.6b01303},
url = {https://juser.fz-juelich.de/record/826304},
}