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@ARTICLE{Brisbois:826585,
author = {Brisbois, Magali and Caes, Sébastien and Sougrati, Moulay
T. and Vertruyen, Bénédicte and Schrijnemakers, Audrey and
Cloots, Rudi and Eshraghi, Nicolas and Hermann, Raphael and
Mahmoud, Abdelfattah and Boschini, Frédéric},
title = {{N}a$_{2}${F}e{PO}$_{4}${F}/multi-walled carbon nanotubes
for lithium-ion batteries: {O}perando {M}össbauer study of
spray-dried composites},
journal = {Solar energy materials $\&$ solar cells},
volume = {148},
issn = {0927-0248},
address = {Amsterdam [u.a.]},
publisher = {NH, Elsevier},
reportid = {FZJ-2017-00804},
pages = {67 - 72},
year = {2016},
abstract = {In order to favor electronic conductivity in sodium iron
fluorophosphate electrodes for lithium- or sodium-ion
batteries, composites of Na2FePO4F with multi-walled carbon
nanotubes (CNTs) were prepared by pilot-scale spray drying.
Addition of multi-walled CNTs in the solution results in an
excellent dispersion of the CNTs within the volume of
Na2FePO4F and not only at the surface of the particles.
Following a heat treatment at 600 °C in argon in order to
reach crystallization, X-ray diffraction and ex situ
Mössbauer spectroscopy revealed the presence of significant
amounts of Fe(III) and maghemite (γ-Fe2O3) in the powder.
However, Na2FePO4F/CNTs composites exhibit good
electrochemical performance when cycling against lithium,
with a discharge capacity of 104 mA h g−1 at C/10 rate and
90 mA h g−1 at 1C rate. Therefore, operando57Fe
transmission Mössbauer spectroscopy analyses were carried
out in order to investigate the evolution of the iron
oxidation state during cycling. During the first discharge,
all the Fe(III) is reduced to Fe(II), explaining the good
electrochemical performance.},
cin = {JCNS-2 / PGI-4 / JARA-FIT},
ddc = {530},
cid = {I:(DE-Juel1)JCNS-2-20110106 / I:(DE-Juel1)PGI-4-20110106 /
$I:(DE-82)080009_20140620$},
pnm = {144 - Controlling Collective States (POF3-144) / 524 -
Controlling Collective States (POF3-524) / 6212 - Quantum
Condensed Matter: Magnetism, Superconductivity (POF3-621) /
6213 - Materials and Processes for Energy and Transport
Technologies (POF3-621) / 6G4 - Jülich Centre for Neutron
Research (JCNS) (POF3-623)},
pid = {G:(DE-HGF)POF3-144 / G:(DE-HGF)POF3-524 /
G:(DE-HGF)POF3-6212 / G:(DE-HGF)POF3-6213 /
G:(DE-HGF)POF3-6G4},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000371944500012},
doi = {10.1016/j.solmat.2015.09.005},
url = {https://juser.fz-juelich.de/record/826585},
}