%0 Journal Article %A Borghardt, Sven %A Winkler, Florian %A Zanolli, Z. %A Verstraete, M. J. %A Barthel, Juri %A Tavabi, A. H. %A Dunin-Borkowski, Rafal %A Kardynal, Beata %T Quantitative agreement between electron-optical phase images of WSe2 and simulations based on electrostatic potentials that include bonding effects %J Physical review letters %V 118 %N 8 %@ 1079-7114 %C College Park, Md. %I APS %M FZJ-2017-01504 %P 086101 %D 2017 %X The quantitative analysis of electron-optical phase images recorded using off-axis electron holography often relies on the use of computer simulations of electron propagation through a sample. However, simulations that make use of the independent atom approximation are known to overestimate experimental phase shifts by approximately 10%, as they neglect bonding effects. Here, we compare experimental and simulated phase images for few-layer WSe2. We show that a combination of pseudopotentials and all-electron density functional theory calculations can be used to obtain accurate mean electron phases, as well as improved atomic-resolution spatial distribution of the electron phase. The comparison demonstrates a perfect contrast match between experimental and simulated atomic-resolution phase images for a sample of precisely known thickness. The low computational cost of this approach makes it suitable for the analysis of large electronic systems, including defects, substitutional atoms, and material interfaces. %F PUB:(DE-HGF)16 %9 Journal Article %U <Go to ISI:>//WOS:000394667600004 %$ pmid:28282203 %R 10.1103/PhysRevLett.118.086101 %U https://juser.fz-juelich.de/record/827368