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@ARTICLE{Chen:827705,
author = {Chen, Chunguang and Li, Dongjiang and Gao, Lu and Harks,
Peter Paul R. M. L. and Eichel, Rüdiger-A. and Notten,
Peter H. L.},
title = {{C}arbon-coated core–shell {L}i 2 {S}@{C} nanocomposites
as high performance cathode materials for lithium–sulfur
batteries},
journal = {Journal of materials chemistry / A},
volume = {5},
number = {4},
issn = {2050-7496},
address = {London [u.a.]},
publisher = {RSC},
reportid = {FZJ-2017-01817},
pages = {1428 - 1433},
year = {2017},
abstract = {Li2S has made the concept of Li–S batteries much more
promising due to the relatively high storage capacity, the
possibility of using Li-free anodes and the increase of
microstructural stability. However, similar to S, Li2S also
suffers from an insulating nature and polysulfide
dissolution problem. The results presented here show a
facile and cost-effective approach by using a plasma
sparking and chemical sulfurization process to synthesize
core–shell Li2S@C nanocomposites. The nanocomposites show
a significantly reduced particle size and well-developed
core–shell architecture, effectively shortening the Li-ion
diffusion distance, enhancing the electronic conductivity
and suppressing the dissolution losses of polysulfides. As a
result, a much improved rate and cycling performance has
been achieved. The method presented in this study offers
good opportunities for scaling up the production of high
performance cathode materials in a simple and low-cost way
to be applied in future generation Li–S batteries.},
cin = {IEK-9},
ddc = {540},
cid = {I:(DE-Juel1)IEK-9-20110218},
pnm = {131 - Electrochemical Storage (POF3-131)},
pid = {G:(DE-HGF)POF3-131},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000395072800011},
doi = {10.1039/C6TA09146F},
url = {https://juser.fz-juelich.de/record/827705},
}