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@ARTICLE{Zhang:827983,
      author       = {Zhang, Miaoyue and Engelhardt, Irina and Šimůnek, Jirka
                      and Bradford, Scott A. and Kasel, Daniela and Berns, Anne E.
                      and Vereecken, Harry and Klumpp, Erwin},
      title        = {{C}o-transport of chlordecone and sulfadiazine in the
                      presence of functionalized multi-walled carbon nanotubes in
                      soils},
      journal      = {Environmental pollution},
      volume       = {221},
      issn         = {0269-7491},
      address      = {Amsterdam [u.a.]},
      publisher    = {Elsevier Science},
      reportid     = {FZJ-2017-02005},
      pages        = {470 - 479},
      year         = {2017},
      abstract     = {Batch and saturated soil column experiments were conducted
                      to investigate sorption and mobility of two 14C-labeled
                      contaminants, the hydrophobic chlordecone (CLD) and the
                      sulfadiazine (SDZ), in the absence or presence of
                      functionalized multi-walled carbon nanotubes (MWCNTs). The
                      transport behaviors of CLD, SDZ, and MWCNTs were studied at
                      environmentally relevant concentrations (0.1–10 mg L−1)
                      and they were applied in the column studies at different
                      times. The breakthrough curves and retention profiles were
                      simulated using a numerical model that accounted for the
                      advective-dispersive transport of all compounds,
                      attachment/detachment of MWCNTs, equilibrium and kinetic
                      sorption of contaminants, and co-transport of contaminants
                      with MWCNTs. The experimental results indicated that the
                      presence of mobile MWCNTs facilitated remobilization of
                      previously deposited CLD and its co-transport into deeper
                      soil layers, while retained MWCNTs enhanced SDZ deposition
                      in the topsoil layers due to the increased adsorption
                      capacity of the soil. The modeling results then demonstrated
                      that the mobility of engineered nanoparticles (ENPs) in the
                      environment and the high affinity and entrapment of
                      contaminants to ENPs were the main reasons for
                      ENP-facilitated contaminant transport. On the other hand,
                      immobile MWCNTs had a less significant impact on the
                      contaminant transport, even though they were still able to
                      enhance the adsorption capacity of the soil.},
      cin          = {IBG-3},
      ddc          = {333.7},
      cid          = {I:(DE-Juel1)IBG-3-20101118},
      pnm          = {255 - Terrestrial Systems: From Observation to Prediction
                      (POF3-255)},
      pid          = {G:(DE-HGF)POF3-255},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000392767900050},
      doi          = {10.1016/j.envpol.2016.12.018},
      url          = {https://juser.fz-juelich.de/record/827983},
}