000828645 001__ 828645
000828645 005__ 20240712084611.0
000828645 0247_ $$2doi$$a10.1021/acs.analchem.7b00631
000828645 0247_ $$2ISSN$$a0003-2700
000828645 0247_ $$2ISSN$$a0096-4484
000828645 0247_ $$2ISSN$$a1520-6882
000828645 0247_ $$2WOS$$aWOS:000399858800059
000828645 0247_ $$2altmetric$$aaltmetric:21833221
000828645 0247_ $$2pmid$$a28345869
000828645 037__ $$aFZJ-2017-02543
000828645 041__ $$aEnglish
000828645 082__ $$a540
000828645 1001_ $$0P:(DE-Juel1)157782$$aMiddendorp, Ronald$$b0$$ufzj
000828645 245__ $$aCharacterization of the Aerosol-Based Synthesis of Uranium Particles as a Potential Reference Material for Microanalytical Methods
000828645 260__ $$aColumbus, Ohio$$bAmerican Chemical Society$$c2017
000828645 3367_ $$2DRIVER$$aarticle
000828645 3367_ $$2DataCite$$aOutput Types/Journal article
000828645 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1493192582_1230
000828645 3367_ $$2BibTeX$$aARTICLE
000828645 3367_ $$2ORCID$$aJOURNAL_ARTICLE
000828645 3367_ $$00$$2EndNote$$aJournal Article
000828645 520__ $$aA process for production of micrometer-sized particles composed of uranium oxide using aerosol spray pyrolysis is characterized with respect to the various production parameters. The aerosol is generated using a vibrating orifice aerosol generator providing monodisperse droplets, which are oxidized in a subsequent heat treatment. Zhe final particles are characterized with microanalytical methods to determine size, shape, internal morphology, and chemical and structural properties in order to assess the suitability of the produced particles as a reference material for microanalytical methods, in particular, for mass spectrometry. It is demonstrated that physicochemical processes during particle formation and the heat treatment to chemically transform particles into an oxide strongly influence the particle shape and the internal morphology. Synchrotron μ-X-ray based techniques combined with μ-Raman spectroscopy have been applied to demonstrate that the obtained microparticles consist of a triuranium octoxide phase. Our studies demonstrate that the process is capable of delivering spherical particles with determined uniform size and elemental as well as chemical composition. The particles therefore represent a suitable base material to fulfill the homogeneity and stability requirements of a reference material for microanalytical methods applied in, for example, international safeguards or nuclear forensics.
000828645 536__ $$0G:(DE-HGF)POF3-161$$a161 - Nuclear Waste Management (POF3-161)$$cPOF3-161$$fPOF III$$x0
000828645 536__ $$0G:(EU-Grant)323300$$aTALISMAN - Transnational Access to Large Infrastructure for a Safe Management of ActiNide (323300)$$c323300$$fFP7-Fission-2012$$x1
000828645 536__ $$0G:(DE-Juel1)IAEA-201204_C$$aIAEA GER SP C 04/2012 - Measurement Methods and Techniques (IAEA-201204_C)$$cIAEA-201204_C$$fIAEA GER SP C 04/2012$$x2
000828645 536__ $$0G:(DE-Juel1)HITEC-20170406$$aHITEC - Helmholtz Interdisciplinary Doctoral Training in Energy and Climate Research (HITEC) (HITEC-20170406)$$cHITEC-20170406$$x3
000828645 588__ $$aDataset connected to CrossRef
000828645 7001_ $$0P:(DE-Juel1)142185$$aDürr, Martin$$b1$$eCorresponding author$$ufzj
000828645 7001_ $$0P:(DE-Juel1)146057$$aKnott, Alexander$$b2
000828645 7001_ $$0P:(DE-HGF)0$$aPointurier, Fabien$$b3
000828645 7001_ $$0P:(DE-HGF)0$$aFerreira Sanchez, Dario$$b4
000828645 7001_ $$0P:(DE-HGF)0$$aSamson, Valerie Ann$$b5
000828645 7001_ $$0P:(DE-HGF)0$$aGrolimund, Daniel$$b6
000828645 773__ $$0PERI:(DE-600)1483443-1$$a10.1021/acs.analchem.7b00631$$gp. acs.analchem.7b00631$$n8$$p4721–4728$$tAnalytical chemistry$$v89$$x1520-6882$$y2017
000828645 8564_ $$uhttp://dx.doi.org/10.1021/acs.analchem.7b00631
000828645 8564_ $$uhttps://juser.fz-juelich.de/record/828645/files/acs%252Eanalchem%252E7b00631.pdf$$yRestricted
000828645 8564_ $$uhttps://juser.fz-juelich.de/record/828645/files/acs%252Eanalchem%252E7b00631.gif?subformat=icon$$xicon$$yRestricted
000828645 8564_ $$uhttps://juser.fz-juelich.de/record/828645/files/acs%252Eanalchem%252E7b00631.jpg?subformat=icon-1440$$xicon-1440$$yRestricted
000828645 8564_ $$uhttps://juser.fz-juelich.de/record/828645/files/acs%252Eanalchem%252E7b00631.jpg?subformat=icon-180$$xicon-180$$yRestricted
000828645 8564_ $$uhttps://juser.fz-juelich.de/record/828645/files/acs%252Eanalchem%252E7b00631.jpg?subformat=icon-640$$xicon-640$$yRestricted
000828645 8564_ $$uhttps://juser.fz-juelich.de/record/828645/files/acs%252Eanalchem%252E7b00631.pdf?subformat=pdfa$$xpdfa$$yRestricted
000828645 909CO $$ooai:juser.fz-juelich.de:828645$$pec_fundedresources$$pVDB$$popenaire
000828645 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)157782$$aForschungszentrum Jülich$$b0$$kFZJ
000828645 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)142185$$aForschungszentrum Jülich$$b1$$kFZJ
000828645 9131_ $$0G:(DE-HGF)POF3-161$$1G:(DE-HGF)POF3-160$$2G:(DE-HGF)POF3-100$$3G:(DE-HGF)POF3$$4G:(DE-HGF)POF$$aDE-HGF$$bEnergie$$lNukleare Entsorgung und Sicherheit sowie Strahlenforschung$$vNuclear Waste Management$$x0
000828645 9141_ $$y2017
000828645 915__ $$0StatID:(DE-HGF)0200$$2StatID$$aDBCoverage$$bSCOPUS
000828645 915__ $$0StatID:(DE-HGF)1030$$2StatID$$aDBCoverage$$bCurrent Contents - Life Sciences
000828645 915__ $$0StatID:(DE-HGF)0600$$2StatID$$aDBCoverage$$bEbsco Academic Search
000828645 915__ $$0StatID:(DE-HGF)0550$$2StatID$$aNo Authors Fulltext
000828645 915__ $$0StatID:(DE-HGF)0100$$2StatID$$aJCR$$bANAL CHEM : 2015
000828645 915__ $$0StatID:(DE-HGF)9905$$2StatID$$aIF >= 5$$bANAL CHEM : 2015
000828645 915__ $$0StatID:(DE-HGF)0150$$2StatID$$aDBCoverage$$bWeb of Science Core Collection
000828645 915__ $$0StatID:(DE-HGF)0110$$2StatID$$aWoS$$bScience Citation Index
000828645 915__ $$0StatID:(DE-HGF)0111$$2StatID$$aWoS$$bScience Citation Index Expanded
000828645 915__ $$0StatID:(DE-HGF)0030$$2StatID$$aPeer Review$$bASC
000828645 915__ $$0StatID:(DE-HGF)1150$$2StatID$$aDBCoverage$$bCurrent Contents - Physical, Chemical and Earth Sciences
000828645 915__ $$0StatID:(DE-HGF)0310$$2StatID$$aDBCoverage$$bNCBI Molecular Biology Database
000828645 915__ $$0StatID:(DE-HGF)0300$$2StatID$$aDBCoverage$$bMedline
000828645 915__ $$0StatID:(DE-HGF)0420$$2StatID$$aNationallizenz
000828645 915__ $$0StatID:(DE-HGF)0199$$2StatID$$aDBCoverage$$bThomson Reuters Master Journal List
000828645 920__ $$lyes
000828645 9201_ $$0I:(DE-Juel1)IEK-6-20101013$$kIEK-6$$lNukleare Entsorgung und Reaktorsicherheit$$x0
000828645 980__ $$ajournal
000828645 980__ $$aVDB
000828645 980__ $$aUNRESTRICTED
000828645 980__ $$aI:(DE-Juel1)IEK-6-20101013
000828645 981__ $$aI:(DE-Juel1)IFN-2-20101013