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| 001 | 828969 | ||
| 005 | 20240712113119.0 | ||
| 024 | 7 | _ | |a 10.1016/j.electacta.2017.01.029 |2 doi |
| 024 | 7 | _ | |a 0013-4686 |2 ISSN |
| 024 | 7 | _ | |a 1873-3859 |2 ISSN |
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| 037 | _ | _ | |a FZJ-2017-02789 |
| 082 | _ | _ | |a 540 |
| 100 | 1 | _ | |a Wagner, Ralf |0 P:(DE-HGF)0 |b 0 |e Corresponding author |
| 245 | _ | _ | |a Magnesium-based additives for the cathode slurry to enable high voltage application of lithium-ion batteries |
| 260 | _ | _ | |a New York, NY [u.a.] |c 2017 |b Elsevier |
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| 520 | _ | _ | |a The kinetic stabilization of the cathode/electrolyte interface is essential to enhance cycle life and safety of lithium-ion batteries at high voltage application. The addition of only 2 wt.% Mg powder to the cathode slurry were found to significantly increase the cycle life of LiNi1/3Co1/3Mn1/3O2/Li half cells upon cycling to 4.6 V vs. Li/Li+, in terms of higher capacity retention, less parasitic reactions and less self-discharge. The presence of dissolved Mg2+ cations in the electrolyte during formation of the cell lead to an increased hydrolysis of the conducting salt LiPF6 and the formation of stable and effective LiPFxOy/Mg(PFxOy)2 species on the charged cathode surface. |
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| 700 | 1 | _ | |a Kraft, Vadim |0 P:(DE-HGF)0 |b 1 |
| 700 | 1 | _ | |a Streipert, Benjamin |0 P:(DE-HGF)0 |b 2 |
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| 700 | 1 | _ | |a Amereller, Marius |0 P:(DE-HGF)0 |b 5 |
| 700 | 1 | _ | |a Korth, Martin |0 P:(DE-HGF)0 |b 6 |
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| 700 | 1 | _ | |a Winter, Martin |0 P:(DE-Juel1)166130 |b 8 |e Corresponding author |u fzj |
| 773 | _ | _ | |a 10.1016/j.electacta.2017.01.029 |g Vol. 228, p. 9 - 17 |0 PERI:(DE-600)1483548-4 |p 9 - 17 |t Electrochimica acta |v 228 |y 2017 |x 0013-4686 |
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