guest ::
| Home > Publications database > Decomposition of Imidazolium-Based Ionic Liquids in Contact with Lithium Metal > print |
| Home > Publications database > Decomposition of Imidazolium-Based Ionic Liquids in Contact with Lithium Metal > print |
| 001 | 828978 | ||
| 005 | 20240712113119.0 | ||
| 024 | 7 | _ | |a 10.1002/cssc.201601496 |2 doi |
| 024 | 7 | _ | |a 1864-5631 |2 ISSN |
| 024 | 7 | _ | |a 1864-564X |2 ISSN |
| 024 | 7 | _ | |a WOS:000398182300009 |2 WOS |
| 024 | 7 | _ | |a altmetric:16559677 |2 altmetric |
| 024 | 7 | _ | |a pmid:27996216 |2 pmid |
| 037 | _ | _ | |a FZJ-2017-02795 |
| 082 | _ | _ | |a 540 |
| 100 | 1 | _ | |a Schmitz, Paulo |0 P:(DE-HGF)0 |b 0 |
| 245 | _ | _ | |a Decomposition of Imidazolium-Based Ionic Liquids in Contact with Lithium Metal |
| 260 | _ | _ | |a Weinheim |c 2017 |b Wiley-VCH |
| 336 | 7 | _ | |a article |2 DRIVER |
| 336 | 7 | _ | |a Output Types/Journal article |2 DataCite |
| 336 | 7 | _ | |a Journal Article |b journal |m journal |0 PUB:(DE-HGF)16 |s 1491569049_659 |2 PUB:(DE-HGF) |
| 336 | 7 | _ | |a ARTICLE |2 BibTeX |
| 336 | 7 | _ | |a JOURNAL_ARTICLE |2 ORCID |
| 336 | 7 | _ | |a Journal Article |0 0 |2 EndNote |
| 520 | _ | _ | |a Ionic liquids (ILs) are considered to be suitable electrolyte components for lithium-metal batteries. Imidazolium cation based ILs were previously found to be applicable for battery systems with a lithium-metal negative electrode. However, herein it is shown that, in contrast to the well-known IL N-butyl-N-methylpyrrolidinium bis[(trifluoromethyl)sulfonyl]imide ([Pyr14][TFSI]), 1-ethyl-3-methylimidazolium bis[(trifluoromethyl)sulfonyl]imide ([C2MIm][TFSI]) and 1-butyl-3-methylimidazolium bis[(trifluoromethyl)sulfonyl]imide ([C4MIm][TFSI]) are chemically unstable versus metallic lithium. A lithium-metal sheet was immersed in pure imidazolium-based IL samples and aged at 60 °C for 28 days. Afterwards, the aged IL samples were investigated to deduce possible decomposition products of the imidazolium cation. The chemical instability of the ILs in contact with lithium metal and a possible decomposition starting point are shown for the first time. Furthermore, the investigated imidazolium-based ILs can be utilized for lithium-metal batteries through the addition of the solid–electrolyte interphase (SEI) film-forming additive fluoroethylene carbonate. |
| 536 | _ | _ | |a 131 - Electrochemical Storage (POF3-131) |0 G:(DE-HGF)POF3-131 |c POF3-131 |f POF III |x 0 |
| 588 | _ | _ | |a Dataset connected to CrossRef |
| 700 | 1 | _ | |a Jakelski, Rene |0 P:(DE-HGF)0 |b 1 |
| 700 | 1 | _ | |a Pyschik, Marcelina |0 P:(DE-HGF)0 |b 2 |
| 700 | 1 | _ | |a Jalkanen, Kirsi |0 P:(DE-HGF)0 |b 3 |
| 700 | 1 | _ | |a Nowak, Sascha |0 P:(DE-HGF)0 |b 4 |
| 700 | 1 | _ | |a Winter, Martin |0 P:(DE-Juel1)166130 |b 5 |u fzj |
| 700 | 1 | _ | |a Bieker, Peter |0 P:(DE-HGF)0 |b 6 |e Corresponding author |
| 773 | _ | _ | |a 10.1002/cssc.201601496 |g Vol. 10, no. 5, p. 876 - 883 |0 PERI:(DE-600)2411405-4 |n 5 |p 876 - 883 |t ChemSusChem |v 10 |y 2017 |x 1864-5631 |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/828978/files/Schmitz_et_al-2017-ChemSusChem.pdf |y Restricted |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/828978/files/Schmitz_et_al-2017-ChemSusChem.gif?subformat=icon |x icon |y Restricted |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/828978/files/Schmitz_et_al-2017-ChemSusChem.jpg?subformat=icon-1440 |x icon-1440 |y Restricted |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/828978/files/Schmitz_et_al-2017-ChemSusChem.jpg?subformat=icon-180 |x icon-180 |y Restricted |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/828978/files/Schmitz_et_al-2017-ChemSusChem.jpg?subformat=icon-640 |x icon-640 |y Restricted |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/828978/files/Schmitz_et_al-2017-ChemSusChem.pdf?subformat=pdfa |x pdfa |y Restricted |
| 909 | C | O | |o oai:juser.fz-juelich.de:828978 |p VDB |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 5 |6 P:(DE-Juel1)166130 |
| 913 | 1 | _ | |a DE-HGF |l Speicher und vernetzte Infrastrukturen |1 G:(DE-HGF)POF3-130 |0 G:(DE-HGF)POF3-131 |2 G:(DE-HGF)POF3-100 |v Electrochemical Storage |x 0 |4 G:(DE-HGF)POF |3 G:(DE-HGF)POF3 |b Energie |
| 914 | 1 | _ | |y 2017 |
| 915 | _ | _ | |a JCR |0 StatID:(DE-HGF)0100 |2 StatID |b CHEMSUSCHEM : 2015 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0200 |2 StatID |b SCOPUS |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0300 |2 StatID |b Medline |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0199 |2 StatID |b Thomson Reuters Master Journal List |
| 915 | _ | _ | |a WoS |0 StatID:(DE-HGF)0110 |2 StatID |b Science Citation Index |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0150 |2 StatID |b Web of Science Core Collection |
| 915 | _ | _ | |a WoS |0 StatID:(DE-HGF)0111 |2 StatID |b Science Citation Index Expanded |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)1150 |2 StatID |b Current Contents - Physical, Chemical and Earth Sciences |
| 915 | _ | _ | |a IF >= 5 |0 StatID:(DE-HGF)9905 |2 StatID |b CHEMSUSCHEM : 2015 |
| 920 | 1 | _ | |0 I:(DE-Juel1)IEK-12-20141217 |k IEK-12 |l Helmholtz-Institut Münster Ionenleiter für Energiespeicher |x 0 |
| 980 | _ | _ | |a journal |
| 980 | _ | _ | |a VDB |
| 980 | _ | _ | |a I:(DE-Juel1)IEK-12-20141217 |
| 980 | _ | _ | |a UNRESTRICTED |
| 981 | _ | _ | |a I:(DE-Juel1)IMD-4-20141217 |
| Library | Collection | CLSMajor | CLSMinor | Language | Author |
|---|