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@ARTICLE{Qian:828981,
      author       = {Qian, Yunxian and Schultz, Carola and Niehoff, Philip and
                      Schwieters, Timo and Nowak, Sascha and Schappacher, Falko M.
                      and Winter, Martin},
      title        = {{I}nvestigations on the electrochemical decomposition of
                      the electrolyte additive vinylene carbonate in {L}i metal
                      half cells and lithium ion full cells},
      journal      = {Journal of power sources},
      volume       = {332},
      issn         = {0378-7753},
      address      = {New York, NY [u.a.]},
      publisher    = {Elsevier},
      reportid     = {FZJ-2017-02798},
      pages        = {60 - 71},
      year         = {2016},
      abstract     = {In this study, the decomposition of vinylene carbonate (VC)
                      additive and its effect on the aging behavior is
                      investigated in Li metal half cells and lithium ion full
                      cells. Four electrolyte systems, the reference electrolyte
                      with three VC additive amounts, i.e., 1, 5 and 10 $vol\%$
                      are examined with commercial LiNi1/3Mn1/3Co1/3O2 (NMC 111)
                      cathode material and mesophase carbon microbeads (MCMB)
                      anode material. The thickness changes of the cathode
                      electrolyte interphase (CEI) and of the solid electrolyte
                      interphase (SEI) after 5 constant current cycles at 0.1C and
                      200 constant current/constant voltage (potential) cycles at
                      1C are investigated for cells containing different amounts
                      of VC. With the help of X-ray photoelectron spectroscopy
                      (XPS) and high-performance liquid chromatography (HPLC), a
                      correlation between CEI thickness change and electrolyte
                      decomposition is figured out. The addition of VC leads to a
                      thin CEI layer and a high capacity retention in a lithium
                      metal half cell. A strong dependence of the performance on
                      the VC concentration is found for half cells that results
                      from the continuous consumption of electrolyte and the
                      electrolyte additive at the Li metal counter electrode. In
                      contrast, for full cells, even 1 $vol\%$ of VC helps to form
                      both a stable CEI and SEI, while a larger amount of VC
                      increases the CEI thickness, electric contact loss and the
                      internal resistance.},
      cin          = {IEK-12},
      ddc          = {620},
      cid          = {I:(DE-Juel1)IEK-12-20141217},
      pnm          = {131 - Electrochemical Storage (POF3-131)},
      pid          = {G:(DE-HGF)POF3-131},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000386643000009},
      doi          = {10.1016/j.jpowsour.2016.09.100},
      url          = {https://juser.fz-juelich.de/record/828981},
}