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@ARTICLE{Rothermel:828987,
author = {Rothermel, Sergej and Evertz, Marco and Kasnatscheew,
Johannes and Qi, Xin and Grützke, Martin and Winter, Martin
and Nowak, Sascha},
title = {{G}raphite {R}ecycling from {S}pent {L}ithium-{I}on
{B}atteries},
journal = {ChemSusChem},
volume = {9},
number = {24},
issn = {1864-5631},
address = {Weinheim},
publisher = {Wiley-VCH},
reportid = {FZJ-2017-02804},
pages = {3473 - 3484},
year = {2016},
abstract = {The present work reports on challenges in utilization of
spent lithium-ion batteries (LIBs)—an increasingly
important aspect associated with a significantly rising
demand for electric vehicles (EVs). In this context, the
feasibility of anode recycling in combination with three
different electrolyte extraction concepts is investigated.
The first method is based on a thermal treatment of graphite
without electrolyte recovery. The second method additionally
utilizes a subcritical carbon-dioxide (subcritical
CO2)-assisted electrolyte extraction prior to thermal
treatment. And the final investigated approach uses
supercritical carbon dioxide (scCO2) as extractant,
subsequently followed by the thermal treatment. It is
demonstrated that the best performance of recycled graphite
anodes can be achieved when electrolyte extraction is
performed using subcritical CO2. Comparative studies reveal
that, in the best case, the electrochemical performance of
recycled graphite exceeds the benchmark consisting of a
newly synthesized graphite anode. As essential efforts
towards electrolyte extraction and cathode recycling have
been made in the past, the electrochemical behavior of
recycled graphite, demonstrating the best performance, is
investigated in combination with a recycled
LiNi1/3Co1/3Mn1/3O2 cathode.},
cin = {IEK-12},
ddc = {540},
cid = {I:(DE-Juel1)IEK-12-20141217},
pnm = {131 - Electrochemical Storage (POF3-131)},
pid = {G:(DE-HGF)POF3-131},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000394571500016},
pubmed = {pmid:27860314},
doi = {10.1002/cssc.201601062},
url = {https://juser.fz-juelich.de/record/828987},
}