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@ARTICLE{Evertz:828995,
      author       = {Evertz, Marco and Horsthemke, Fabian and Kasnatscheew,
                      Johannes and Börner, Markus and Winter, Martin and Nowak,
                      Sascha},
      title        = {{U}nraveling transition metal dissolution of
                      {L}i$_{1.04}${N}i$_{1/3}${C}o$_{1/3}${M}n$_{1/3}${O}$_{2}$
                      ({NCM} 111) in lithium ion full cells by using the total
                      reflection {X}-ray fluorescence technique},
      journal      = {Journal of power sources},
      volume       = {329},
      issn         = {0378-7753},
      address      = {New York, NY [u.a.]},
      publisher    = {Elsevier},
      reportid     = {FZJ-2017-02812},
      pages        = {364 - 371},
      year         = {2016},
      abstract     = {In this work we investigated the transition metal
                      dissolution of the layered cathode material
                      Li1.04Ni1/3Co1/3Mn1/3O2 in dependence on the cycle number
                      and cut-off cell voltage during charge by using the total
                      reflection X-ray fluorescence technique for the elemental
                      analysis of the specific lithium ion battery degradation
                      products.We could show that with ongoing cycling transition
                      metal dissolution from the cathode increased over time.
                      However, it was less pronounced at 4.3 V compared to
                      elevated charge cut-off voltages of 4.6 V. After a maximum
                      of 100 cycles, we detected an overall transition metal loss
                      of 0.2 wt‰ in relation to the whole cathode active
                      material for cells cycled to 4.3 V. At an increased charge
                      cut-off voltage of 4.6 V, 4.5 wt‰ transition metal loss in
                      relation to the whole cathode active material could be
                      detected. The corresponding transition metal dissolution
                      induced capacity loss at the cathode could thus be
                      attributed to 1.2 mAh g−1. Compared to the overall
                      capacity loss of 80 mAh g−1 of the complete cell after 100
                      galvanostatic charge/discharge cycles the value is quite
                      low. Hence, the overall full cell capacity fade cannot be
                      assigned exclusively to the transition metal dissolution
                      induced cathode fading.},
      cin          = {IEK-12},
      ddc          = {620},
      cid          = {I:(DE-Juel1)IEK-12-20141217},
      pnm          = {131 - Electrochemical Storage (POF3-131)},
      pid          = {G:(DE-HGF)POF3-131},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000384852800042},
      doi          = {10.1016/j.jpowsour.2016.08.099},
      url          = {https://juser.fz-juelich.de/record/828995},
}