guest ::
| Home > Publications database > Ester Modified Pyrrolidinium Based Ionic Liquids as Electrolyte Component Candidates in Rechargeable Lithium Batteries > print |
| Home > Publications database > Ester Modified Pyrrolidinium Based Ionic Liquids as Electrolyte Component Candidates in Rechargeable Lithium Batteries > print |
| 001 | 829009 | ||
| 005 | 20240709081932.0 | ||
| 024 | 7 | _ | |a 10.1002/zaac.201500554 |2 doi |
| 024 | 7 | _ | |a 0044-2313 |2 ISSN |
| 024 | 7 | _ | |a 0372-7874 |2 ISSN |
| 024 | 7 | _ | |a 0863-1778 |2 ISSN |
| 024 | 7 | _ | |a 0863-1786 |2 ISSN |
| 024 | 7 | _ | |a 1521-3749 |2 ISSN |
| 024 | 7 | _ | |a WOS:000368040700030 |2 WOS |
| 037 | _ | _ | |a FZJ-2017-02826 |
| 082 | _ | _ | |a 540 |
| 100 | 1 | _ | |a Cao, Xia |0 P:(DE-HGF)0 |b 0 |e Corresponding author |
| 245 | _ | _ | |a Ester Modified Pyrrolidinium Based Ionic Liquids as Electrolyte Component Candidates in Rechargeable Lithium Batteries |
| 260 | _ | _ | |a Weinheim |c 2015 |b Wiley-VCH |
| 336 | 7 | _ | |a article |2 DRIVER |
| 336 | 7 | _ | |a Output Types/Journal article |2 DataCite |
| 336 | 7 | _ | |a Journal Article |b journal |m journal |0 PUB:(DE-HGF)16 |s 1491803022_30238 |2 PUB:(DE-HGF) |
| 336 | 7 | _ | |a ARTICLE |2 BibTeX |
| 336 | 7 | _ | |a JOURNAL_ARTICLE |2 ORCID |
| 336 | 7 | _ | |a Journal Article |0 0 |2 EndNote |
| 520 | _ | _ | |a Room temperature ionic liquids (RTILs), especially pyrrolidinium based RTILs with bis(trifluoromethane-sulfonyl)imide (TFSI) as counterion, are frequently proposed as promising electrolyte component candidates thanks to their high thermal as well as high oxidation stability. In order to avoid a resource intensive experimental approach, mainly based on trial and error experiments, a computational screening method for pre-selecting suitable candidate molecules was adopted and three homologous series compounds were synthesized by modifying the cation structure of pyrrolidinium RTILs. The obtained high purity RTILs: methyl-methylcarboxymethyl pyrrolidinium TFSI (MMMPyrTFSI), methyl-ethylcarboxymethyl pyrrolidinium TFSI (MEMPyrTFSI) and methylpropylcarboxymethyl pyrrolidinium TFSI (MPMPyrTFSI) revealed excellent thermal stabilities higher than 300 °C. Furthermore, MMMPyrTFSI and MPMPyrTFSI exhibit high oxidation stability up to 5.4 V vs. Li/Li+. No aluminum corrosion of current collector was observed at 5 V vs. Li/Li+. In addition to that, these RTILs display a superior salt (LiTFSI) solubility (3.0–3.5 M), compared to the unmodified RTIL 1-butyl-1-methylpyrrolidinium TFSI (Pyr14TFSI) (1.5–2.0 M) at room temperature. All these properties make novel ester modified RTILs promising and interesting candidates for application in rechargeable lithium batteries. |
| 536 | _ | _ | |a 131 - Electrochemical Storage (POF3-131) |0 G:(DE-HGF)POF3-131 |c POF3-131 |f POF III |x 0 |
| 588 | _ | _ | |a Dataset connected to CrossRef |
| 700 | 1 | _ | |a Röser, Stephan |0 P:(DE-HGF)0 |b 1 |
| 700 | 1 | _ | |a Rezaei Rad, Babak |0 P:(DE-Juel1)167131 |b 2 |u fzj |
| 700 | 1 | _ | |a He, Xin |0 P:(DE-Juel1)169319 |b 3 |u fzj |
| 700 | 1 | _ | |a Streipert, Benjamin |0 P:(DE-HGF)0 |b 4 |
| 700 | 1 | _ | |a Winter, Martin |0 P:(DE-Juel1)166130 |b 5 |e Corresponding author |u fzj |
| 700 | 1 | _ | |a Cekic-Laskovic, Isidora |0 P:(DE-Juel1)171204 |b 6 |u fzj |
| 773 | _ | _ | |a 10.1002/zaac.201500554 |g Vol. 641, no. 14, p. 2536 - 2542 |0 PERI:(DE-600)1481139-x |n 14 |p 2536 - 2542 |t Zeitschrift für anorganische und allgemeine Chemie |v 641 |y 2015 |x 0044-2313 |
| 909 | C | O | |o oai:juser.fz-juelich.de:829009 |p VDB |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 2 |6 P:(DE-Juel1)167131 |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 3 |6 P:(DE-Juel1)169319 |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 5 |6 P:(DE-Juel1)166130 |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 6 |6 P:(DE-Juel1)171204 |
| 913 | 1 | _ | |a DE-HGF |l Speicher und vernetzte Infrastrukturen |1 G:(DE-HGF)POF3-130 |0 G:(DE-HGF)POF3-131 |2 G:(DE-HGF)POF3-100 |v Electrochemical Storage |x 0 |4 G:(DE-HGF)POF |3 G:(DE-HGF)POF3 |b Energie |
| 915 | _ | _ | |a Nationallizenz |0 StatID:(DE-HGF)0420 |2 StatID |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0200 |2 StatID |b SCOPUS |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0300 |2 StatID |b Medline |
| 915 | _ | _ | |a JCR |0 StatID:(DE-HGF)0100 |2 StatID |b Z ANORG ALLG CHEM : 2015 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0199 |2 StatID |b Thomson Reuters Master Journal List |
| 915 | _ | _ | |a WoS |0 StatID:(DE-HGF)0110 |2 StatID |b Science Citation Index |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0150 |2 StatID |b Web of Science Core Collection |
| 915 | _ | _ | |a WoS |0 StatID:(DE-HGF)0111 |2 StatID |b Science Citation Index Expanded |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)1150 |2 StatID |b Current Contents - Physical, Chemical and Earth Sciences |
| 915 | _ | _ | |a IF < 5 |0 StatID:(DE-HGF)9900 |2 StatID |
| 920 | 1 | _ | |0 I:(DE-Juel1)IEK-12-20141217 |k IEK-12 |l Helmholtz-Institut Münster Ionenleiter für Energiespeicher |x 0 |
| 980 | _ | _ | |a journal |
| 980 | _ | _ | |a VDB |
| 980 | _ | _ | |a I:(DE-Juel1)IEK-12-20141217 |
| 980 | _ | _ | |a UNRESTRICTED |
| 981 | _ | _ | |a I:(DE-Juel1)IMD-4-20141217 |
| Library | Collection | CLSMajor | CLSMinor | Language | Author |
|---|