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@ARTICLE{Vogl:829010,
author = {Vogl, U. S. and Lux, S. F. and Das, P. and Weber, A. and
Placke, T. and Kostecki, R. and Winter, M.},
title = {{T}he {M}echanism of {SEI} {F}ormation on {S}ingle
{C}rystal {S}i(100), {S}i(110) and {S}i(111) {E}lectrodes},
journal = {Journal of the Electrochemical Society},
volume = {162},
number = {12},
issn = {1945-7111},
address = {Pennington, NJ},
publisher = {Electrochemical Soc.},
reportid = {FZJ-2017-02827},
pages = {A2281 - A2288},
year = {2015},
abstract = {Subsequent to our previous studies on the SEI formation
mechanism on the single crystal silicon (100) surface, here
we report on complementary studies of the SEI formation on
Si surfaces with the crystal orientations (111) and (110).
The differences in electrochemical behavior of the different
crystal orientations are discussed - especially with regard
to the effect of the SEI forming electrolyte additives
fluoroethylene carbonate (FEC) and vinylene carbonate (VC)
added to ethylene carbonate (EC)/diethyl carbonate (DEC)
based electrolytes. Fourier transform infrared spectroscopy
(FTIR) of the SEI during early stages of SEI formation and
physico-chemical investigations (wetting behavior) indicate
a strong dependence of the chemical composition of the SEI
on the surface orientation and the electrolyte composition
during the early stages of lithiation of Si. However, at a
higher lithiation degree less difference in the chemical
composition of the SEI can be observed. These findings are
in agreement with those made for the SEI formation on the
Si(100) surface.},
cin = {IEK-12},
ddc = {540},
cid = {I:(DE-Juel1)IEK-12-20141217},
pnm = {131 - Electrochemical Storage (POF3-131)},
pid = {G:(DE-HGF)POF3-131},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000363600300009},
doi = {10.1149/2.0361512jes},
url = {https://juser.fz-juelich.de/record/829010},
}