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@ARTICLE{Vogl:829013,
author = {Vogl, U. S. and Lux, S. F. and Crumlin, E. J. and Liu, Z.
and Terborg, L. and Winter, M. and Kostecki, R.},
title = {{T}he {M}echanism of {SEI} {F}ormation on a {S}ingle
{C}rystal {S}i(100) {E}lectrode},
journal = {Journal of the Electrochemical Society},
volume = {162},
number = {4},
issn = {1945-7111},
address = {Pennington, NJ},
publisher = {Electrochemical Soc.},
reportid = {FZJ-2017-02830},
pages = {A603 - A607},
year = {2015},
abstract = {A fundamental study of interfacial phenomena on a Si(100)
single crystal electrode in organic carbonate-based
electrolytes was carried out. The SEI formation on the
Si(100) single crystal electrode was investigated as a
function of the electrolyte composition, electrode potential
and LixSi lithiation degree. Fourier transform infrared
spectroscopy (FTIR) and X-ray photon spectroscopy (XPS)
studies of the SEI layer during early stages of SEI
formation indicate a strong dependence of the SEI
composition on the electrolyte composition. However, the
influence of the electrolyte composition becomes negligible
at low potentials, when lithium alloys with Si and forms
amorphous LixSi. The effect of vinylene carbonate (VC) and
fluoroethylene carbonate (FEC) electrolyte additives on the
composition of the SEI layer was evaluated.},
cin = {IEK-12},
ddc = {540},
cid = {I:(DE-Juel1)IEK-12-20141217},
pnm = {131 - Electrochemical Storage (POF3-131)},
pid = {G:(DE-HGF)POF3-131},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000349827200014},
doi = {10.1149/2.0391504jes},
url = {https://juser.fz-juelich.de/record/829013},
}