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@ARTICLE{He:829334,
      author       = {He, Xin and Wang, Rui and Stan, Marian Cristian and
                      Paillard, Elie and Wang, Jun and Frielinghaus, Henrich and
                      Li, Jie},
      title        = {{I}n {S}itu {I}nvestigations on the {S}tructural and
                      {M}orphological {C}hanges of {M}etal {P}hosphides as {A}node
                      {M}aterials in {L}ithium-{I}on {B}atteries},
      journal      = {Advanced materials interfaces},
      volume       = {4},
      number       = {7},
      issn         = {2196-7350},
      address      = {Weinheim},
      publisher    = {Wiley-VCH},
      reportid     = {FZJ-2017-03053},
      pages        = {1601047 -},
      year         = {2017},
      abstract     = {The binary metal phosphides (MP, M = Cu, Fe, Sn, Sb)
                      compounds are of great interest as negative electrode
                      materials for high energy density lithium-ion batteries.
                      However, the morphology and structural changes at the
                      nanoscale upon electrochemical (de)lithiation are not clear
                      yet, which require further detailed investigation. In situ
                      neutron scattering technique is utilized to investigate and
                      compare the morphological changes of copper phosphide and
                      tin phosphide during the initial cycle. By coupling with
                      scanning electron microscopy investigation, the surface
                      activities of the electrodes at different electrochemical
                      states, including the solid electrolyte interphase
                      formation, swelling and recovering, cracks appearance, and
                      stripping at nanoscale of the material particles are
                      evaluated. With in situ X-ray diffraction measurement,the
                      energy storage mechanism is further explained. This work
                      demonstrates useful techniques to analyze the detailed
                      fatigue mechanisms of the activematerial, and provides new
                      insights of the nanostructural changes of anode materials
                      reacting with lithium via conversion and alloying.},
      cin          = {IEK-12 / JCNS (München) ; Jülich Centre for Neutron
                      Science JCNS (München) ; JCNS-FRM-II},
      ddc          = {540},
      cid          = {I:(DE-Juel1)IEK-12-20141217 /
                      I:(DE-Juel1)JCNS-FRM-II-20110218},
      pnm          = {6G4 - Jülich Centre for Neutron Research (JCNS) (POF3-623)
                      / 131 - Electrochemical Storage (POF3-131)},
      pid          = {G:(DE-HGF)POF3-6G4 / G:(DE-HGF)POF3-131},
      experiment   = {EXP:(DE-MLZ)KWS1-20140101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000399037600005},
      doi          = {10.1002/admi.201601047},
      url          = {https://juser.fz-juelich.de/record/829334},
}