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@ARTICLE{Jones:830116,
author = {Jones, Robert O. and Ahlstedt, O. and Akola, Jaakko and
Ropo, M.},
title = {{D}ensity functional study of structure and dynamics in
liquid antimony and {S}b n clusters},
journal = {The journal of chemical physics},
volume = {146},
number = {19},
issn = {1089-7690},
address = {Melville, NY},
publisher = {American Institute of Physics},
reportid = {FZJ-2017-03699},
pages = {194502},
year = {2017},
abstract = {Density functional/molecular dynamics simulations have been
performed on liquid antimony (588 atoms and six temperatures
between 600 K and 1300 K) and on neutral Sb clusters with up
to 14 atoms. We study structural patterns (coordination
numbers, bond angles, and ring patterns, structure factors,
pair distribution functions) and dynamical properties
(vibration frequencies, diffusion constants, power spectra,
dynamical structure factors, viscosity) and compare with
available experimental results and with the results of our
previous simulations on Bi. Three short covalent bonds
characteristic of pnictogens are common in the clusters, and
higher temperatures lead in the liquid to broader bond angle
distributions, larger total cavity volumes, and weaker
correlations between neighboring bond lengths. There are
clear similarities between the properties of Sb and Bi
aggregates},
cin = {IAS-1 / PGI-1 / JARA-FIT / JARA-HPC},
ddc = {540},
cid = {I:(DE-Juel1)IAS-1-20090406 / I:(DE-Juel1)PGI-1-20110106 /
$I:(DE-82)080009_20140620$ / $I:(DE-82)080012_20140620$},
pnm = {142 - Controlling Spin-Based Phenomena (POF3-142) / 143 -
Controlling Configuration-Based Phenomena (POF3-143) /
Density functional calculations with molecular dynamics --
amorphous and crystalline alloys $(jiff05_20150501)$ /
Density functional simulations of phases of elements
$(jiff37_20121101)$},
pid = {G:(DE-HGF)POF3-142 / G:(DE-HGF)POF3-143 /
$G:(DE-Juel1)jiff05_20150501$ /
$G:(DE-Juel1)jiff37_20121101$},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000401776300025},
pubmed = {pmid:28527440},
doi = {10.1063/1.4983219},
url = {https://juser.fz-juelich.de/record/830116},
}