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@ARTICLE{Fittschen:830497,
author = {Fittschen, Christa and Assaf, Emmanuel and Vereecken, Luc},
title = {{E}xperimental and {T}heoretical {I}nvestigation of the
{R}eaction {NO} + {OH} + {O} 2 → {HO} 2 + {NO} 2},
journal = {The journal of physical chemistry / A},
volume = {121},
number = {24},
issn = {1089-5639},
address = {Washington, DC},
publisher = {Soc.},
reportid = {FZJ-2017-04038},
pages = {4652–4657},
year = {2017},
abstract = {Photolysis of NO2 is the only major pathway for O3
formation as products from the reaction of OH and NO under
atmospheric conditions in competition to the formation of
HONO has been investigated experimentally and theoretically.
Experiments have been carried out by directly measuring the
formation of HO2 radicals using laser photolysis coupled to
cw-CRDS. OH radicals have been generated from the reaction
of F atoms with H2O, and absolute HO2 and OH profiles have
been recorded at different NO concentrations. The potential
energy surface has been calculated and the rate constant has
been obtained from RRKM master equation modeling. Both
experiment and theory show that the OH + NO reaction in the
presence of O2 bath gas is not a competitive source of HO2 +
NO2.},
cin = {IEK-8},
ddc = {530},
cid = {I:(DE-Juel1)IEK-8-20101013},
pnm = {243 - Tropospheric trace substances and their
transformation processes (POF3-243)},
pid = {G:(DE-HGF)POF3-243},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000404202100008},
pubmed = {pmid:28541043},
doi = {10.1021/acs.jpca.7b02499},
url = {https://juser.fz-juelich.de/record/830497},
}