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@ARTICLE{Naqash:834098,
author = {Naqash, Sahir and Ma, Qianli and Tietz, Frank and Guillon,
Olivier},
title = {{N}a3{Z}r2({S}i{O}4)2({PO}4) prepared by a
solution-assisted solid state reaction},
journal = {Solid state ionics},
volume = {302},
issn = {0167-2738},
address = {Amsterdam [u.a.]},
publisher = {Elsevier Science},
reportid = {FZJ-2017-04099},
pages = {83 - 91},
year = {2017},
abstract = {The Na+ super-ionic conductor Na3Zr2(SiO4)2(PO4), known as
the original NASICON material, is a promising solid-state
electrolyte that can be used for sodium batteries. A
solution-assisted solid state reaction (SA-SSR) method has
been developed for its synthesis. The method is convenient,
low-cost, and has potential for large scale production. The
total conductivity of the sample synthesized by SA-SSR is 1
× 10− 3 S cm− 1 at 25 °C, which is one of the highest
reported data of this composition after conventional
processing of the ceramic powder. To rationalize the
advantages of the method, a comparison of powders and
ceramics prepared by the Pechini and SA-SSR methods was
carried out. Scanning electron microscopy, X-ray diffraction
and impedance spectroscopy were used to investigate the
products of both synthesis routes and the possible reasons
of the high quality of SA-SSR samples are discussed.},
cin = {IEK-1 / IEK-12 / JARA-ENERGY},
ddc = {530},
cid = {I:(DE-Juel1)IEK-1-20101013 / I:(DE-Juel1)IEK-12-20141217 /
$I:(DE-82)080011_20140620$},
pnm = {131 - Electrochemical Storage (POF3-131) / HITEC -
Helmholtz Interdisciplinary Doctoral Training in Energy and
Climate Research (HITEC) (HITEC-20170406)},
pid = {G:(DE-HGF)POF3-131 / G:(DE-Juel1)HITEC-20170406},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000397688300017},
doi = {10.1016/j.ssi.2016.11.004},
url = {https://juser.fz-juelich.de/record/834098},
}