Hauptseite > Publikationsdatenbank > Na3Zr2(SiO4)2(PO4) prepared by a solution-assisted solid state reaction > print |
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100 | 1 | _ | |a Naqash, Sahir |0 P:(DE-Juel1)165865 |b 0 |e Corresponding author |u fzj |
245 | _ | _ | |a Na3Zr2(SiO4)2(PO4) prepared by a solution-assisted solid state reaction |
260 | _ | _ | |a Amsterdam [u.a.] |c 2017 |b Elsevier Science |
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520 | _ | _ | |a The Na+ super-ionic conductor Na3Zr2(SiO4)2(PO4), known as the original NASICON material, is a promising solid-state electrolyte that can be used for sodium batteries. A solution-assisted solid state reaction (SA-SSR) method has been developed for its synthesis. The method is convenient, low-cost, and has potential for large scale production. The total conductivity of the sample synthesized by SA-SSR is 1 × 10− 3 S cm− 1 at 25 °C, which is one of the highest reported data of this composition after conventional processing of the ceramic powder. To rationalize the advantages of the method, a comparison of powders and ceramics prepared by the Pechini and SA-SSR methods was carried out. Scanning electron microscopy, X-ray diffraction and impedance spectroscopy were used to investigate the products of both synthesis routes and the possible reasons of the high quality of SA-SSR samples are discussed. |
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700 | 1 | _ | |a Guillon, Olivier |0 P:(DE-Juel1)161591 |b 3 |u fzj |
773 | _ | _ | |a 10.1016/j.ssi.2016.11.004 |g Vol. 302, p. 83 - 91 |0 PERI:(DE-600)1500750-9 |p 83 - 91 |t Solid state ionics |v 302 |y 2017 |x 0167-2738 |
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