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@ARTICLE{Muthmann:834343,
author = {Muthmann, Matthias and Krutyeva, Margarita and Willner,
Lutz and Allgaier, J. and Richter, Dieter and Zorn, Reiner
and Ohl, Michael and Rebbin, Vivian and Lindner, Peter},
title = {{D}escription of poly(ethylenepropylene) confined in
nanopores by a modified {R}ouse model},
journal = {The journal of chemical physics},
volume = {146},
number = {20},
issn = {1089-7690},
address = {Melville, NY},
publisher = {American Institute of Physics},
reportid = {FZJ-2017-04318},
pages = {203309 -},
year = {2017},
abstract = {A recent model for unentangled polymer chains in
confinement [M. Dolgushev and M. Krutyeva, Macromol. Theory
Simul. 21, 565 (2012)] is scrutinized by small-angle neutron
scattering (SANS) with respect to its static prediction, the
single-chain structure factor. We find a remarkable
agreement although the model simplifies the effect of the
confinement to a harmonic potential. The effective
confinement size from fits of SANS data with the model
agrees well with the actual pore size. Starting from this
result we discuss the possibility of an experiment on the
dynamic structure factor predicted by the model. It turns
out that such an experiment would need a large ratio polymer
dimension/pore size which is difficult but not impossible to
achieve},
cin = {ICS-1 / Neutronenstreuung ; JCNS-1 / JCNS-SNS},
ddc = {540},
cid = {I:(DE-Juel1)ICS-1-20110106 / I:(DE-Juel1)JCNS-1-20110106 /
I:(DE-Juel1)JCNS-SNS-20110128},
pnm = {551 - Functional Macromolecules and Complexes (POF3-551) /
6G4 - Jülich Centre for Neutron Research (JCNS) (POF3-623)
/ 6215 - Soft Matter, Health and Life Sciences (POF3-621)},
pid = {G:(DE-HGF)POF3-551 / G:(DE-HGF)POF3-6G4 /
G:(DE-HGF)POF3-6215},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000401778900011},
pubmed = {pmid:28571384},
doi = {10.1063/1.4975977},
url = {https://juser.fz-juelich.de/record/834343},
}