000836204 001__ 836204
000836204 005__ 20240712101004.0
000836204 0247_ $$2doi$$a10.5194/amt-2017-231
000836204 0247_ $$2Handle$$a2128/15038
000836204 037__ $$aFZJ-2017-05325
000836204 082__ $$a550
000836204 1001_ $$0P:(DE-Juel1)7363$$aFuchs, Hendrik$$b0$$eCorresponding author
000836204 245__ $$aComparison of OH reactivity measurements in the atmospheric simulation chamber SAPHIR
000836204 260__ $$aKatlenburg-Lindau$$bCopernicus$$c2017
000836204 3367_ $$2DRIVER$$aarticle
000836204 3367_ $$2DataCite$$aOutput Types/Journal article
000836204 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1501577931_13619
000836204 3367_ $$2BibTeX$$aARTICLE
000836204 3367_ $$2ORCID$$aJOURNAL_ARTICLE
000836204 3367_ $$00$$2EndNote$$aJournal Article
000836204 520__ $$aHydroxyl (OH) radical reactivity (kOH) has been measured for 18 years with different measurement techniques. In order to compare the performances of instruments deployed in the field, two campaigns were conducted performing experiments in the atmospheric simulation chamber SAPHIR at Forschungszentrum Jülich in October 2015 and April 2016. Chemical conditions were chosen either to be representative of the atmosphere or to test potential limitations of instruments. All types of instruments that are currently used for atmospheric measurements took part in one of the two campaigns. The results of these campaigns demonstrate that OH reactivity can be accurately measured for a wide range of atmospherically relevant chemical conditions (e.g. water vapor, nitrogen oxides, various organic compounds) by all instruments. The precision of the measurements (limit of detection < 1 s−1 at a time resolution of 30 seconds to a few minutes) is higher for instruments directly detecting hydroxyl radicals, whereas the indirect Comparative Reactivity Method (CRM) has a higher limit of detection of 2 s−1 at a time resolution of 10 to 15 min. The performances of the instruments were systematically tested by stepwise increasing, for example, the concentrations of carbon monoxide (CO), water vapor or nitric oxide (NO). In further experiments, mixtures of organic reactants were injected in the chamber to simulate urban and forested environments. Overall, the results show that instruments are capable of measuring OH reactivity in the presence of CO, alkanes, alkenes and aromatic compounds. The transmission efficiency in Teflon inlet lines could have introduced systematic errors in measurements for low-volatile organic compounds in some instruments. CRM instruments exhibited a larger scatter in the data compared to the other instruments. The largest differences to reference measurements or to calculated reactivity were observed by CRM instruments in the presence of terpenes and oxygenated organic compounds (mixing ratio of OH reactants were up to 10 ppbv). In some of these experiments, only a small fraction of the reactivity is detected. The accuracy of CRM measurements is most likely limited by the corrections that need to be applied in order to account for known effects of, for example, deviations from pseudo-first order conditions, nitrogen oxides or water vapor on the measurement. Methods to derive these corrections vary among the different CRM instruments. Measurements by a flow-tube instrument combined with the direct detection of OH by chemical ionization mass spectrometry (CIMS) show limitations in cases of high reactivity and high NO concentrations, but were accurate for low reactivity (< 15 s−1) and low NO (< 5 ppbv) conditions.
000836204 536__ $$0G:(DE-HGF)POF3-243$$a243 - Tropospheric trace substances and their transformation processes (POF3-243)$$cPOF3-243$$fPOF III$$x0
000836204 536__ $$0G:(DE-Juel1)HITEC-20170406$$aHITEC - Helmholtz Interdisciplinary Doctoral Training in Energy and Climate Research (HITEC) (HITEC-20170406)$$cHITEC-20170406$$x1
000836204 588__ $$aDataset connected to CrossRef
000836204 7001_ $$0P:(DE-Juel1)166537$$aNovelli, Anna$$b1
000836204 7001_ $$0P:(DE-Juel1)166277$$aRolletter, Michael$$b2$$ufzj
000836204 7001_ $$0P:(DE-Juel1)16326$$aHofzumahaus, Andreas$$b3
000836204 7001_ $$0P:(DE-HGF)0$$aPfannerstill, Eva Y.$$b4
000836204 7001_ $$0P:(DE-HGF)0$$aKessel, Stephan$$b5
000836204 7001_ $$0P:(DE-HGF)0$$aEdtbauer, Achim$$b6
000836204 7001_ $$0P:(DE-HGF)0$$aWilliams, Jonathan$$b7
000836204 7001_ $$0P:(DE-HGF)0$$aMichoud, Vincent$$b8
000836204 7001_ $$0P:(DE-HGF)0$$aDusanter, Sebastien$$b9
000836204 7001_ $$0P:(DE-HGF)0$$aLocoge, Nadine$$b10
000836204 7001_ $$0P:(DE-HGF)0$$aZannoni, Nora$$b11
000836204 7001_ $$0P:(DE-HGF)0$$aGros, Valerie$$b12
000836204 7001_ $$0P:(DE-HGF)0$$aTruong, Francois$$b13
000836204 7001_ $$0P:(DE-HGF)0$$aSarda-Esteve, Roland$$b14
000836204 7001_ $$00000-0002-0828-4218$$aCryer, Danny R.$$b15
000836204 7001_ $$0P:(DE-HGF)0$$aBrumby, Charlotte A.$$b16
000836204 7001_ $$0P:(DE-HGF)0$$aWhalley, Lisa K.$$b17
000836204 7001_ $$0P:(DE-HGF)0$$aStone, Daniel$$b18
000836204 7001_ $$0P:(DE-HGF)0$$aSeakins, Paul W.$$b19
000836204 7001_ $$0P:(DE-HGF)0$$aHeard, Dwayne E.$$b20
000836204 7001_ $$0P:(DE-HGF)0$$aSchoemaecker, Coralie$$b21
000836204 7001_ $$0P:(DE-Juel1)170025$$aBlocquet, Marion$$b22$$ufzj
000836204 7001_ $$0P:(DE-HGF)0$$aCoudert, Sebastien$$b23
000836204 7001_ $$0P:(DE-HGF)0$$aBatut, Sebastien$$b24
000836204 7001_ $$0P:(DE-HGF)0$$aFittschen, Christa$$b25
000836204 7001_ $$0P:(DE-HGF)0$$aThames, Alexander B.$$b26
000836204 7001_ $$0P:(DE-HGF)0$$aBrune, William H.$$b27
000836204 7001_ $$0P:(DE-HGF)0$$aErnest, Cheryl$$b28
000836204 7001_ $$0P:(DE-HGF)0$$aHarder, Hartwig$$b29
000836204 7001_ $$0P:(DE-HGF)0$$aMuller, Jenifer B. A.$$b30
000836204 7001_ $$0P:(DE-HGF)0$$aElste, Thomas$$b31
000836204 7001_ $$0P:(DE-HGF)0$$aKubistin, Dagmar$$b32
000836204 7001_ $$0P:(DE-Juel1)6627$$aAndres, Stefanie$$b33$$ufzj
000836204 7001_ $$0P:(DE-Juel1)2693$$aBohn, Birger$$b34$$ufzj
000836204 7001_ $$0P:(DE-Juel1)161442$$aHohaus, Thorsten$$b35$$ufzj
000836204 7001_ $$0P:(DE-Juel1)16342$$aHolland, Frank$$b36$$ufzj
000836204 7001_ $$0P:(DE-Juel1)6775$$aLi, Xin$$b37$$ufzj
000836204 7001_ $$0P:(DE-Juel1)16347$$aRohrer, Franz$$b38$$ufzj
000836204 7001_ $$0P:(DE-Juel1)4528$$aKiendler-Scharr, Astrid$$b39$$ufzj
000836204 7001_ $$0P:(DE-Juel1)5344$$aTillmann, Ralf$$b40$$ufzj
000836204 7001_ $$0P:(DE-Juel1)2367$$aWegener, Robert$$b41$$ufzj
000836204 7001_ $$0P:(DE-Juel1)159354$$aYu, Zhujun$$b42$$ufzj
000836204 7001_ $$0P:(DE-HGF)0$$aZou, Qi$$b43
000836204 7001_ $$0P:(DE-Juel1)16324$$aWahner, Andreas$$b44
000836204 773__ $$0PERI:(DE-600)2507817-3$$a10.5194/amt-2017-231$$gp. 1 - 56$$p1 - 56$$tAtmospheric measurement techniques discussions$$v 231$$x1867-8610$$y2017
000836204 8564_ $$uhttps://juser.fz-juelich.de/record/836204/files/amt-2017-231.pdf$$yOpenAccess
000836204 8564_ $$uhttps://juser.fz-juelich.de/record/836204/files/amt-2017-231.gif?subformat=icon$$xicon$$yOpenAccess
000836204 8564_ $$uhttps://juser.fz-juelich.de/record/836204/files/amt-2017-231.jpg?subformat=icon-1440$$xicon-1440$$yOpenAccess
000836204 8564_ $$uhttps://juser.fz-juelich.de/record/836204/files/amt-2017-231.jpg?subformat=icon-180$$xicon-180$$yOpenAccess
000836204 8564_ $$uhttps://juser.fz-juelich.de/record/836204/files/amt-2017-231.jpg?subformat=icon-640$$xicon-640$$yOpenAccess
000836204 8564_ $$uhttps://juser.fz-juelich.de/record/836204/files/amt-2017-231.pdf?subformat=pdfa$$xpdfa$$yOpenAccess
000836204 909CO $$ooai:juser.fz-juelich.de:836204$$pdnbdelivery$$pVDB$$pdriver$$popen_access$$popenaire
000836204 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)7363$$aForschungszentrum Jülich$$b0$$kFZJ
000836204 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)166537$$aForschungszentrum Jülich$$b1$$kFZJ
000836204 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)166277$$aForschungszentrum Jülich$$b2$$kFZJ
000836204 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)16326$$aForschungszentrum Jülich$$b3$$kFZJ
000836204 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)170025$$aForschungszentrum Jülich$$b22$$kFZJ
000836204 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)6627$$aForschungszentrum Jülich$$b33$$kFZJ
000836204 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)2693$$aForschungszentrum Jülich$$b34$$kFZJ
000836204 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)161442$$aForschungszentrum Jülich$$b35$$kFZJ
000836204 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)16342$$aForschungszentrum Jülich$$b36$$kFZJ
000836204 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)6775$$aForschungszentrum Jülich$$b37$$kFZJ
000836204 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)16347$$aForschungszentrum Jülich$$b38$$kFZJ
000836204 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)4528$$aForschungszentrum Jülich$$b39$$kFZJ
000836204 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)5344$$aForschungszentrum Jülich$$b40$$kFZJ
000836204 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)2367$$aForschungszentrum Jülich$$b41$$kFZJ
000836204 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)159354$$aForschungszentrum Jülich$$b42$$kFZJ
000836204 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)16324$$aForschungszentrum Jülich$$b44$$kFZJ
000836204 9131_ $$0G:(DE-HGF)POF3-243$$1G:(DE-HGF)POF3-240$$2G:(DE-HGF)POF3-200$$3G:(DE-HGF)POF3$$4G:(DE-HGF)POF$$aDE-HGF$$bErde und Umwelt$$lAtmosphäre und Klima$$vTropospheric trace substances and their transformation processes$$x0
000836204 9141_ $$y2017
000836204 915__ $$0StatID:(DE-HGF)0600$$2StatID$$aDBCoverage$$bEbsco Academic Search
000836204 915__ $$0LIC:(DE-HGF)CCBY4$$2HGFVOC$$aCreative Commons Attribution CC BY 4.0
000836204 915__ $$0StatID:(DE-HGF)0501$$2StatID$$aDBCoverage$$bDOAJ Seal
000836204 915__ $$0StatID:(DE-HGF)0500$$2StatID$$aDBCoverage$$bDOAJ
000836204 915__ $$0StatID:(DE-HGF)0510$$2StatID$$aOpenAccess
000836204 915__ $$0StatID:(DE-HGF)0030$$2StatID$$aPeer Review$$bASC
000836204 920__ $$lyes
000836204 9201_ $$0I:(DE-Juel1)IEK-8-20101013$$kIEK-8$$lTroposphäre$$x0
000836204 9801_ $$aFullTexts
000836204 980__ $$ajournal
000836204 980__ $$aVDB
000836204 980__ $$aUNRESTRICTED
000836204 980__ $$aI:(DE-Juel1)IEK-8-20101013
000836204 981__ $$aI:(DE-Juel1)ICE-3-20101013