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@INBOOK{Frielinghaus:836824,
author = {Frielinghaus, Henrich and Pyckhout-Hintzen, Wim},
title = {{C}hapter 10: {N}eutron {S}cattering on different states of
polymer/clay compounds: {F}romsolution to dry states.},
address = {Amsterdam},
publisher = {Elsevier Science},
reportid = {FZJ-2017-05866},
isbn = {978-0-323-46153-5},
pages = {327-362},
year = {2017},
comment = {Clay-Polymer Nanocomposites},
booktitle = {Clay-Polymer Nanocomposites},
abstract = {Nanocomposites [1] in general have gained importance in
nowadays products leading to improved performance of these
complex compound materials. The structure of the solid
particles is not limited in terms of shape in advance, but
their specific function is tightly connected to their shape.
Scattering experiments [2, 3, 4] are often employed to
supervise production routes and the final performance, but
not all possibilities of scattering experiments are
exploited due to several reasons: Engineers need to enter
the unknown stage of scattering experiments, and the
scattering experts need to simplify their experience to
simple usable recipes that are applicable and reliable. This
process is still ongoing and the authors hope to contribute
to this highly interesting journey. The advantages [5, 6] of
clay-polymer nanocomposites [7] are already explored:
mechanical improvements [8, 9], fire retardancy [5], and gas
permittivity [10]. A good dispersion state is not always
given a priori, and special strategies need to be employed
[11, 12]: One might need strong shear fields, or even
chemical modifications which either cover the clay with
surfactants to reduce the surface tension or directly graft
polymers to the particles. The obtained results of such
measures need to be explored. Here scattering experiments
come into play. They allow for characterizing the dispersion
state and give feedback to the dispersion strategy. When
employing microscopic models to connect the nanostructure
with the macroscopic behavior, new insights might be gained
that would allow for predictive tailoring of the macroscopic
behavior. For instance the prediction of rheological
properties of clay containing systems is still a demanding
task.},
cin = {JCNS (München) ; Jülich Centre for Neutron Science JCNS
(München) ; JCNS-FRM-II / ICS-1 / Neutronenstreuung ;
JCNS-1},
cid = {I:(DE-Juel1)JCNS-FRM-II-20110218 /
I:(DE-Juel1)ICS-1-20110106 / I:(DE-Juel1)JCNS-1-20110106},
pnm = {6215 - Soft Matter, Health and Life Sciences (POF3-621) /
6G15 - FRM II / MLZ (POF3-6G15) / 6G4 - Jülich Centre for
Neutron Research (JCNS) (POF3-623)},
pid = {G:(DE-HGF)POF3-6215 / G:(DE-HGF)POF3-6G15 /
G:(DE-HGF)POF3-6G4},
experiment = {EXP:(DE-MLZ)KWS1-20140101 / EXP:(DE-MLZ)J-NSE-20140101 /
EXP:(DE-Juel1)SNS-NSE-20150203},
typ = {PUB:(DE-HGF)7},
url = {https://juser.fz-juelich.de/record/836824},
}