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000836973 1001_ $$0P:(DE-HGF)0$$aHuttmann, Felix$$b0$$eCorresponding author
000836973 245__ $$aOn-Surface Synthesis of Sandwich Molecular Nanowires on Graphene
000836973 260__ $$aWashington, DC$$bAmerican Chemical Society$$c2017
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000836973 520__ $$aWe demonstrate a new synthesis route for the growth of organometallic sandwich molecular nanowires, taking the example of Eu-cyclooctatetraene (EuCot), a predicted ferromagnetic semiconductor. We employ simultaneous exposure of Cot molecules and Eu vapor in ultrahigh vacuum to an inert substrate, such as graphene. Using a Cot excess under temperature conditions of a finite residence time of the molecule, the reactand diffusion confined to two dimensions results in a clean product of ultralong wires. In situ scanning tunneling microscopy reveals not only their molecular structure but also a rich and intriguing growth morphology. The new on-surface synthesis permits experimental access to a largely unexplored class of one-dimensional organometallic systems with potential for exciting electronic and magnetic properties.
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000836973 7001_ $$0P:(DE-HGF)0$$aSchleheck, Nicolas$$b1
000836973 7001_ $$0P:(DE-Juel1)130513$$aAtodiresei, Nicolae$$b2$$ufzj
000836973 7001_ $$0P:(DE-HGF)0$$aMichely, Thomas$$b3
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