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@ARTICLE{Huttmann:836973,
author = {Huttmann, Felix and Schleheck, Nicolas and Atodiresei,
Nicolae and Michely, Thomas},
title = {{O}n-{S}urface {S}ynthesis of {S}andwich {M}olecular
{N}anowires on {G}raphene},
journal = {Journal of the American Chemical Society},
volume = {139},
number = {29},
issn = {1520-5126},
address = {Washington, DC},
publisher = {American Chemical Society},
reportid = {FZJ-2017-05995},
pages = {9895 - 9900},
year = {2017},
abstract = {We demonstrate a new synthesis route for the growth of
organometallic sandwich molecular nanowires, taking the
example of Eu-cyclooctatetraene (EuCot), a predicted
ferromagnetic semiconductor. We employ simultaneous exposure
of Cot molecules and Eu vapor in ultrahigh vacuum to an
inert substrate, such as graphene. Using a Cot excess under
temperature conditions of a finite residence time of the
molecule, the reactand diffusion confined to two dimensions
results in a clean product of ultralong wires. In situ
scanning tunneling microscopy reveals not only their
molecular structure but also a rich and intriguing growth
morphology. The new on-surface synthesis permits
experimental access to a largely unexplored class of
one-dimensional organometallic systems with potential for
exciting electronic and magnetic properties.},
cin = {IAS-1 / PGI-1 / JARA-FIT / JARA-HPC},
ddc = {540},
cid = {I:(DE-Juel1)IAS-1-20090406 / I:(DE-Juel1)PGI-1-20110106 /
$I:(DE-82)080009_20140620$ / $I:(DE-82)080012_20140620$},
pnm = {143 - Controlling Configuration-Based Phenomena (POF3-143)},
pid = {G:(DE-HGF)POF3-143},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:28682606},
UT = {WOS:000417342500005},
doi = {10.1021/jacs.7b03381},
url = {https://juser.fz-juelich.de/record/836973},
}