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| Hauptseite > Publikationsdatenbank > On-Surface Synthesis of Sandwich Molecular Nanowires on Graphene > print |
| Hauptseite > Publikationsdatenbank > On-Surface Synthesis of Sandwich Molecular Nanowires on Graphene > print |
| 001 | 836973 | ||
| 005 | 20210129231138.0 | ||
| 024 | 7 | _ | |a 10.1021/jacs.7b03381 |2 doi |
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| 037 | _ | _ | |a FZJ-2017-05995 |
| 041 | _ | _ | |a English |
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| 100 | 1 | _ | |a Huttmann, Felix |0 P:(DE-HGF)0 |b 0 |e Corresponding author |
| 245 | _ | _ | |a On-Surface Synthesis of Sandwich Molecular Nanowires on Graphene |
| 260 | _ | _ | |a Washington, DC |c 2017 |b American Chemical Society |
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| 520 | _ | _ | |a We demonstrate a new synthesis route for the growth of organometallic sandwich molecular nanowires, taking the example of Eu-cyclooctatetraene (EuCot), a predicted ferromagnetic semiconductor. We employ simultaneous exposure of Cot molecules and Eu vapor in ultrahigh vacuum to an inert substrate, such as graphene. Using a Cot excess under temperature conditions of a finite residence time of the molecule, the reactand diffusion confined to two dimensions results in a clean product of ultralong wires. In situ scanning tunneling microscopy reveals not only their molecular structure but also a rich and intriguing growth morphology. The new on-surface synthesis permits experimental access to a largely unexplored class of one-dimensional organometallic systems with potential for exciting electronic and magnetic properties. |
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| 700 | 1 | _ | |a Schleheck, Nicolas |0 P:(DE-HGF)0 |b 1 |
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| 700 | 1 | _ | |a Michely, Thomas |0 P:(DE-HGF)0 |b 3 |
| 773 | _ | _ | |a 10.1021/jacs.7b03381 |g Vol. 139, no. 29, p. 9895 - 9900 |0 PERI:(DE-600)1472210-0 |n 29 |p 9895 - 9900 |t Journal of the American Chemical Society |v 139 |y 2017 |x 1520-5126 |
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