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@ARTICLE{Senkovskiy:836981,
author = {Senkovskiy, Boris V. and Fedorov, Alexander V. and Haberer,
Danny and Farjam, Mani and Simonov, Konstantin A. and
Preobrajenski, Alexei B. and Mårtensson, Niels and
Atodiresei, Nicolae and Caciuc, Vasile and Blügel, Stefan
and Rosch, Achim and Verbitskiy, Nikolay I. and Hell, Martin
and Evtushinsky, Daniil V. and German, Raphael and
Marangoni, Tomas and van Loosdrecht, Paul H. M. and Fischer,
Felix R. and Grüneis, Alexander},
title = {{S}emiconductor-to-{M}etal {T}ransition and {Q}uasiparticle
{R}enormalization in {D}oped {G}raphene {N}anoribbons2},
journal = {Advanced electronic materials},
volume = {3},
number = {4},
issn = {2199-160X},
address = {Chichester},
publisher = {Wiley},
reportid = {FZJ-2017-06003},
pages = {1600490},
year = {2017},
abstract = {A semiconductor-to-metal transition in N = 7 armchair
graphene nanoribbons causes drastic changes in its electron
and phonon system. By using angle-resolved photoemission
spectroscopy of lithium-doped graphene nanoribbons, a
quasiparticle band gap renormalization from 2.4 to 2.1 eV is
observed. Reaching high doping levels (0.05 electrons per
atom), it is found that the effective mass of the conduction
band carriers increases to a value equal to the free
electron mass. This giant increase in the effective mass by
doping is a means to enhance the density of states at the
Fermi level which can have palpable impact on the transport
and optical properties. Electron doping also reduces the
Raman intensity by one order of magnitude, and results in
relatively small (4 cm−1) hardening of the G phonon and
softening of the D phonon. This suggests the importance of
both lattice expansion and dynamic effects. The present work
highlights that doping of a semiconducting 1D system is
strikingly different from its 2D or 3D counterparts and
introduces doped graphene nanoribbons as a new tunable
quantum material with high potential for basic research and
applications.},
cin = {IAS-1 / PGI-1 / JARA-FIT / JARA-HPC},
ddc = {621.3},
cid = {I:(DE-Juel1)IAS-1-20090406 / I:(DE-Juel1)PGI-1-20110106 /
$I:(DE-82)080009_20140620$ / $I:(DE-82)080012_20140620$},
pnm = {142 - Controlling Spin-Based Phenomena (POF3-142) / 143 -
Controlling Configuration-Based Phenomena (POF3-143)},
pid = {G:(DE-HGF)POF3-142 / G:(DE-HGF)POF3-143},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000399448600005},
doi = {10.1002/aelm.201600490},
url = {https://juser.fz-juelich.de/record/836981},
}