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@ARTICLE{Wang:837187,
      author       = {Wang, Jun and He, Xin and Paillard, Elie-Elisée and
                      Laszczynski, Nina and Li, Jie and Passerini, Stefano},
      title        = {{L}ithium- and {M}anganese-{R}ich {O}xide {C}athode
                      {M}aterials for {H}igh-{E}nergy {L}ithium {I}on {B}atteries},
      journal      = {Advanced energy materials},
      volume       = {6},
      number       = {21},
      issn         = {1614-6832},
      address      = {Weinheim},
      publisher    = {Wiley-VCH},
      reportid     = {FZJ-2017-06166},
      pages        = {1600906 -},
      year         = {2016},
      abstract     = {Layered lithium- and manganese-rich oxides (LMROs),
                      described as xLi2MnO3·(1–x)LiMO2 or Li1+yM1–yO2 (M =
                      Mn, Ni, Co, etc., 0 < x <1, 0 < y ≤ 0.33), have attracted
                      much attention as cathode materials for lithium ion
                      batteries in recent years. They exhibit very promising
                      capacities, up to above 300 mA h g−1, due to transition
                      metal redox reactions and unconventional oxygen anion redox
                      reaction. However, they suffer from structural degradation
                      and severe voltage fade (i.e., decreasing energy storage)
                      upon cycling, which are plaguing their practical
                      application. Thus, this review will aim to describe the
                      pristine structure, high-capacity mechanisms and structure
                      evolutions of LMROs. Also, recent progress associated with
                      understanding and mitigating the voltage decay of LMROs will
                      be discussed. Several approaches to solve this problem, such
                      as adjusting cycling voltage window and chemical
                      composition, optimizing synthesis strategy, controlling
                      morphology, doping, surface modification, constructing
                      core-shell and layered-spinel hetero structures, are
                      described in detail.},
      cin          = {IEK-12},
      ddc          = {600},
      cid          = {I:(DE-Juel1)IEK-12-20141217},
      pnm          = {131 - Electrochemical Storage (POF3-131)},
      pid          = {G:(DE-HGF)POF3-131},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000387664800006},
      doi          = {10.1002/aenm.201600906},
      url          = {https://juser.fz-juelich.de/record/837187},
}