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@ARTICLE{He:837190,
author = {He, Xin and Wang, Jun and Qiu, Bao and Paillard,
Elie-Elisée and Ma, Chuze and Cao, Xia and Liu, Haodong and
Stan, Marian Cristian and Liu, Haidong and Gallash, Tobias
and Meng, Y. Shirley and Li, Jie},
title = {{D}urable high-rate capability {N}a$_{0.44}$ {M}n{O}$_{2}$
cathode material for sodium-ion batteries},
journal = {Nano energy},
volume = {27},
issn = {2211-2855},
address = {Amsterdam [u.a.]},
publisher = {Elsevier},
reportid = {FZJ-2017-06169},
pages = {602 - 610},
year = {2016},
abstract = {Monocrystalline orthorhombic Na0.44MnO2 nanoplate as a
potential cathode material for sodium-ion batteries has been
synthesized by a template-assisted sol-gel method. It
exhibits high crystallinity, pure phase and homogeneous size
distribution. During the synthesis, acidic and reductive
conditions are applied to limit the production of
unfavorable Birnessite phase in the precursor, and colloidal
polystyrene is included to avoid morphology collapse during
the gel formation and particle elongation in one direction.
The decompositions of polystyrene and citric acid during
high temperature firing offer a reductive carbothermal
condition which can suppress the formation of unidimensional
particles, and limit particle growth along the [001]
direction. As a consequence, the material delivers 96 mAh
g−1 discharge capacity at 10 C $(86\%$ of 0.1 C capacity)
and maintains $97.8\%$ capacity after 100 cycles at 0.5 C.
Such superior rate capability and cycling stability of this
material are among the best to date, suggesting its great
interest in practical applications.},
cin = {IEK-12},
ddc = {540},
cid = {I:(DE-Juel1)IEK-12-20141217},
pnm = {131 - Electrochemical Storage (POF3-131)},
pid = {G:(DE-HGF)POF3-131},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000384910500067},
doi = {10.1016/j.nanoen.2016.07.021},
url = {https://juser.fz-juelich.de/record/837190},
}