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@ARTICLE{Muratova:837504,
      author       = {Muratova, I. S. and Mikhelson, K. N. and Ermolenko, Yu. and
                      Offenhäusser, A. and Mourzina, Yu.},
      title        = {{O}n “resistance overpotential” caused by a potential
                      drop along the ultrathin high aspect ratio gold nanowire
                      electrodes in cyclic voltammetry},
      journal      = {Journal of solid state electrochemistry},
      volume       = {20},
      number       = {12},
      issn         = {1433-0768},
      address      = {Berlin},
      publisher    = {Springer},
      reportid     = {FZJ-2017-06400},
      pages        = {3359 - 3365},
      year         = {2016},
      abstract     = {High aspect ratio ultrathin (d < 10 nm) gold nanowires
                      deposited on Si/SiO2 substrate are used as working
                      electrodes for measuring cyclic voltammograms (CVs) in
                      aqueous solutions of ferrocenemethanol and potassium
                      hexacyanoferrate. The broadening of the peak separation as
                      compared with that at a solid working electrode is explained
                      as a result of the potential drop (“resistance
                      overpotential”) along nanowires and nanowire network. The
                      change in the CV shape over a sequence of scans is ascribed
                      to a gradual breakup of individual nanowires and the
                      respective transition of the linear diffusion to
                      hemispherical diffusion regularities.},
      cin          = {ICS-8 / JARA-FIT},
      ddc          = {540},
      cid          = {I:(DE-Juel1)ICS-8-20110106 / $I:(DE-82)080009_20140620$},
      pnm          = {523 - Controlling Configuration-Based Phenomena (POF3-523)},
      pid          = {G:(DE-HGF)POF3-523},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000388506300016},
      doi          = {10.1007/s10008-016-3280-x},
      url          = {https://juser.fz-juelich.de/record/837504},
}