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@ARTICLE{Skripnikova:837512,
      author       = {Skripnikova, Tatiana A. and Starikova, Anna A. and
                      Shumilova, Galina I. and Ermolenko, Yuri E. and Pendin,
                      Andrey A. and Mourzina, Youlia},
      title        = {{T}owards stabilization of the potential response of
                      {M}n({III}) tetraphenylporphyrin-based solid-state
                      electrodes with selectivity for salicylate ions},
      journal      = {Journal of solid state electrochemistry},
      volume       = {21},
      number       = {8},
      issn         = {1433-0768},
      address      = {Berlin},
      publisher    = {Springer},
      reportid     = {FZJ-2017-06408},
      pages        = {2269 - 2279},
      year         = {2017},
      abstract     = {We report a new type of solid-state electrode (type I) of a
                      simple design with polyvinyl chloride membranes based on
                      Mn(III) tetraphenylporphyrin and with graphite as the
                      electronically conducting substrate. Enlargement of the
                      membrane/graphite contact area by soaking graphite in the
                      plasticizer with subsequent conditioning of the electrode at
                      30 °C allowed us to shorten the time required to achieve
                      steady potential values of the sensors to just 3 days. These
                      electrodes do not require a specially added RedOx system in
                      the transducer layer. Stabilization of the EMF response of
                      type I electrodes is compared to type II electrodes which
                      contain a Cu0/Cu2+ RedOx couple in the transducer layer.
                      Type I sensors are suitable for measuring the salicylate ion
                      concentration in the clinically important concentration
                      range down to 2.5 × 10−4 M with a sensitivity to
                      salicylate ion of −59.0 mV decade−1 in solutions with a
                      high constant background of chloride ions of 0.12 M at pH =
                      5.3, making this a promising technique for an effective
                      design of solid-contact ion-selective electrodes with
                      polymeric sensing membranes.},
      cin          = {ICS-8},
      ddc          = {540},
      cid          = {I:(DE-Juel1)ICS-8-20110106},
      pnm          = {523 - Controlling Configuration-Based Phenomena (POF3-523)},
      pid          = {G:(DE-HGF)POF3-523},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000406177400012},
      doi          = {10.1007/s10008-017-3575-6},
      url          = {https://juser.fz-juelich.de/record/837512},
}