001     837518
005     20240619091229.0
024 7 _ |a 10.1002/chem.201605924
|2 doi
024 7 _ |a 0947-6539
|2 ISSN
024 7 _ |a 1521-3765
|2 ISSN
024 7 _ |a WOS:000399326500016
|2 WOS
024 7 _ |a 2128/15928
|2 Handle
024 7 _ |a altmetric:17831522
|2 altmetric
024 7 _ |a pmid:28182315
|2 pmid
037 _ _ |a FZJ-2017-06414
082 _ _ |a 540
100 1 _ |a Krause, Kay J.
|0 P:(DE-Juel1)156197
|b 0
245 _ _ |a The Influence of Supporting Ions on the Electrochemical Detection of Individual Silver Nanoparticles: Understanding the Shape and Frequency of Current Transients in Nano-impacts
260 _ _ |a Weinheim
|c 2017
|b Wiley-VCH
336 7 _ |a article
|2 DRIVER
336 7 _ |a Output Types/Journal article
|2 DataCite
336 7 _ |a Journal Article
|b journal
|m journal
|0 PUB:(DE-HGF)16
|s 1511445722_4950
|2 PUB:(DE-HGF)
336 7 _ |a ARTICLE
|2 BibTeX
336 7 _ |a JOURNAL_ARTICLE
|2 ORCID
336 7 _ |a Journal Article
|0 0
|2 EndNote
520 _ _ |a We report the influence of electrolyte composition and concentration on the stochastic amperometric detection of individual silver nanoparticles at microelectrode arrays and show that the sensor response at certain electrode potentials is dependent on both the conductivity of the electrolyte and the concentration of chloride ions. We further demonstrate that the chloride concentration in solution heavily influences the characteristic current spike shape of recorded nanoparticle impacts: While typically too short to be resolved in the measured current, the spike widths are significantly broadened at low chloride concentrations below 10 mm and range into the millisecond regime. The analysis of more than 25 000 spikes reveals that this effect can be explained by the diffusive mass transport of chloride ions to the nanoparticle, which limits the oxidation rate of individual silver nanoparticles to silver chloride at the chosen electrode potential.
536 _ _ |a 523 - Controlling Configuration-Based Phenomena (POF3-523)
|0 G:(DE-HGF)POF3-523
|c POF3-523
|f POF III
|x 0
588 _ _ |a Dataset connected to CrossRef
700 1 _ |a Brings, Fabian
|0 P:(DE-Juel1)161443
|b 1
700 1 _ |a Schnitker, Jan
|0 P:(DE-Juel1)140152
|b 2
700 1 _ |a Kätelhön, Enno
|0 P:(DE-Juel1)128700
|b 3
700 1 _ |a Rinklin, Philipp
|0 P:(DE-Juel1)140264
|b 4
700 1 _ |a Mayer, Dirk
|0 P:(DE-Juel1)128707
|b 5
700 1 _ |a Compton, Richard G.
|0 P:(DE-HGF)0
|b 6
700 1 _ |a Lemay, Serge G.
|0 P:(DE-HGF)0
|b 7
700 1 _ |a Offenhäusser, Andreas
|0 P:(DE-Juel1)128713
|b 8
700 1 _ |a Wolfrum, Bernhard
|0 P:(DE-Juel1)128745
|b 9
|e Corresponding author
773 _ _ |a 10.1002/chem.201605924
|g Vol. 23, no. 19, p. 4638 - 4643
|0 PERI:(DE-600)1478547-x
|n 19
|p 4638 - 4643
|t Chemistry - a European journal
|v 23
|y 2017
|x 0947-6539
856 4 _ |y Published on 2017-11-23. Available in OpenAccess from 2018-11-23.
|u https://juser.fz-juelich.de/record/837518/files/chem.201605924.pdf
856 4 _ |y Published on 2017-11-23. Available in OpenAccess from 2018-11-23.
|x icon
|u https://juser.fz-juelich.de/record/837518/files/chem.201605924.gif?subformat=icon
856 4 _ |y Published on 2017-11-23. Available in OpenAccess from 2018-11-23.
|x icon-1440
|u https://juser.fz-juelich.de/record/837518/files/chem.201605924.jpg?subformat=icon-1440
856 4 _ |y Published on 2017-11-23. Available in OpenAccess from 2018-11-23.
|x icon-180
|u https://juser.fz-juelich.de/record/837518/files/chem.201605924.jpg?subformat=icon-180
856 4 _ |y Published on 2017-11-23. Available in OpenAccess from 2018-11-23.
|x icon-640
|u https://juser.fz-juelich.de/record/837518/files/chem.201605924.jpg?subformat=icon-640
856 4 _ |y Published on 2017-11-23. Available in OpenAccess from 2018-11-23.
|x pdfa
|u https://juser.fz-juelich.de/record/837518/files/chem.201605924.pdf?subformat=pdfa
909 C O |o oai:juser.fz-juelich.de:837518
|p openaire
|p open_access
|p driver
|p VDB
|p dnbdelivery
910 1 _ |a Forschungszentrum Jülich
|0 I:(DE-588b)5008462-8
|k FZJ
|b 1
|6 P:(DE-Juel1)161443
910 1 _ |a Forschungszentrum Jülich
|0 I:(DE-588b)5008462-8
|k FZJ
|b 2
|6 P:(DE-Juel1)140152
910 1 _ |a Forschungszentrum Jülich
|0 I:(DE-588b)5008462-8
|k FZJ
|b 5
|6 P:(DE-Juel1)128707
910 1 _ |a Forschungszentrum Jülich
|0 I:(DE-588b)5008462-8
|k FZJ
|b 8
|6 P:(DE-Juel1)128713
910 1 _ |a Forschungszentrum Jülich
|0 I:(DE-588b)5008462-8
|k FZJ
|b 9
|6 P:(DE-Juel1)128745
913 1 _ |a DE-HGF
|b Key Technologies
|l Future Information Technology - Fundamentals, Novel Concepts and Energy Efficiency (FIT)
|1 G:(DE-HGF)POF3-520
|0 G:(DE-HGF)POF3-523
|2 G:(DE-HGF)POF3-500
|v Controlling Configuration-Based Phenomena
|x 0
|4 G:(DE-HGF)POF
|3 G:(DE-HGF)POF3
914 1 _ |y 2017
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0200
|2 StatID
|b SCOPUS
915 _ _ |a Embargoed OpenAccess
|0 StatID:(DE-HGF)0530
|2 StatID
915 _ _ |a JCR
|0 StatID:(DE-HGF)0100
|2 StatID
|b CHEM-EUR J : 2015
915 _ _ |a IF >= 5
|0 StatID:(DE-HGF)9905
|2 StatID
|b CHEM-EUR J : 2015
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0150
|2 StatID
|b Web of Science Core Collection
915 _ _ |a WoS
|0 StatID:(DE-HGF)0110
|2 StatID
|b Science Citation Index
915 _ _ |a WoS
|0 StatID:(DE-HGF)0111
|2 StatID
|b Science Citation Index Expanded
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)1150
|2 StatID
|b Current Contents - Physical, Chemical and Earth Sciences
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0310
|2 StatID
|b NCBI Molecular Biology Database
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0300
|2 StatID
|b Medline
915 _ _ |a Nationallizenz
|0 StatID:(DE-HGF)0420
|2 StatID
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0199
|2 StatID
|b Thomson Reuters Master Journal List
920 _ _ |l yes
920 1 _ |0 I:(DE-Juel1)ICS-8-20110106
|k ICS-8
|l Bioelektronik
|x 0
920 1 _ |0 I:(DE-Juel1)PGI-8-20110106
|k PGI-8
|l Bioelektronik
|x 1
980 1 _ |a FullTexts
980 _ _ |a journal
980 _ _ |a VDB
980 _ _ |a UNRESTRICTED
980 _ _ |a I:(DE-Juel1)ICS-8-20110106
980 _ _ |a I:(DE-Juel1)PGI-8-20110106
981 _ _ |a I:(DE-Juel1)IBI-3-20200312


LibraryCollectionCLSMajorCLSMinorLanguageAuthor
Marc 21