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@ARTICLE{Lftner:837519,
author = {Lüftner, Daniel and Weiß, Simon and Yang, Xiaosheng and
Hurdax, Philipp and Feyer, Vitaliy and Gottwald, Alexander
and Koller, Georg and Soubatch, Serguei and Puschnig, Peter
and Ramsey, Michael G. and Tautz, F. S.},
title = {{U}nderstanding the photoemission distribution of strongly
interacting two-dimensional overlayers},
journal = {Physical review / B},
volume = {96},
number = {12},
issn = {2469-9950},
address = {Woodbury, NY},
publisher = {Inst.},
reportid = {FZJ-2017-06415},
pages = {125402},
year = {2017},
abstract = {Photoemission tomography (PT), the analysis of the
photoemission intensity distribution within the plane wave
final-state approximation, is being established as a useful
tool for extracting the electronic and geometric structure
of weakly interacting organic overlayers. Here we present a
simple method for extending PT, which until now has been
based on the calculations of isolated molecules. By
including the substrate and a damped plane-wave final state,
we are able to simulate the photoemission intensity
distribution of two-dimensional molecular overlayers with
both strong intermolecular and molecule-substrate
interactions, here demonstrated for the model system
3,4,9,10-perylene-tetracarboxylic dianhydride (PTCDA) on
Cu(100). It is shown that the interaction and hybridization
of the lowest unoccupied molecular orbital of PTCDA with
substrate states leads to its occupation and the formation
of a strongly dispersing intermolecular band, whose
experimental magnitude of 1.1 eV and k-space periodicity is
well reproduced theoretically.},
cin = {PGI-3},
ddc = {530},
cid = {I:(DE-Juel1)PGI-3-20110106},
pnm = {143 - Controlling Configuration-Based Phenomena (POF3-143)},
pid = {G:(DE-HGF)POF3-143},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000409255700009},
doi = {10.1103/PhysRevB.96.125402},
url = {https://juser.fz-juelich.de/record/837519},
}