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000837850 1001_ $$0P:(DE-HGF)0$$aErini, Nina$$b0
000837850 245__ $$aThe Effect of Surface Site Ensembles on the Activity and Selectivity of Ethanol Electrooxidation by Octahedral PtNiRh Nanoparticles
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000837850 520__ $$aDirect ethanol fuel cells are attractive power sources based on a biorenewable, high energy-density fuel. Their efficiency is limited by the lack of active anode materials which catalyze the breaking of the C−C bond coupled to the 12-electron oxidation to CO2. We report shape-controlled PtNiRh octahedral ethanol oxidation electrocatalysts with excellent activity and previously unachieved low onset potentials as low as 0.1 V vs. RHE, while being highly selective to complete oxidation to CO2. Our comprehensive characterization and in situ electrochemical ATR studies suggest that the formation of a ternary surface site ensemble around the octahedral Pt3Ni1Rhx nanoparticles plays a crucial mechanistic role for this behavior.
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000837850 7001_ $$0P:(DE-HGF)0$$aBeermann, Vera$$b1
000837850 7001_ $$0P:(DE-Juel1)166087$$aGocyla, Martin$$b2
000837850 7001_ $$0P:(DE-HGF)0$$aGliech, Manuel$$b3
000837850 7001_ $$0P:(DE-Juel1)130695$$aHeggen, Marc$$b4
000837850 7001_ $$0P:(DE-Juel1)144121$$aDunin-Borkowski, Rafal$$b5
000837850 7001_ $$0P:(DE-HGF)0$$aStrasser, Peter$$b6$$eCorresponding author
000837850 773__ $$0PERI:(DE-600)1479266-7$$a10.1002/ange.201702332$$gVol. 129, no. 23, p. 6633 - 6638$$n23$$p6633 - 6638$$tAngewandte Chemie$$v129$$x0044-8249$$y2017
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