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000837873 1001_ $$0P:(DE-Juel1)159404$$aRamasamy, M.$$b0$$ufzj
000837873 245__ $$aStructural and chemical stability of high performance Ce 0.8 Gd 0.2 O 2-δ - FeCo 2 O 4 dual phase oxygen transport membranes
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000837873 520__ $$aCeramic oxide membranes are widely being researched for Carbon Capture and Storage/Utilization sector applications. Foreseen applications of these membranes are oxygen generation for oxyfuel combustion in e.g. power plants, glass-, cement- or steel production. Major drawback with Mixed Ionic and Electronic Conducting (MIEC) perovskite structure membranes is their limited long term stability at high temperatures in aggressive atmospheres. Dual phase composite membranes have been reported to excel overcoming this drawback. In addition to performance evaluation, Ce0.8Gd0.2O2-δ – FeCo2O4 (CGO-FCO) membranes were subjected to stability test in flue gas conditions closely mimicking industrial flue gas atmosphere. The dual phase composites are investigated for their phase stability at the operating temperature of 850 °C in a gradient of oxygen chemical potential. The composites were also exposed to a series of gas mixtures over a period of time at their operating temperature to test for the chemical stability. CGO-FCO membranes are identified to possess chemical stability in gas mixtures of CO2, SO2 along with oxygen over a period of 200 h at 850 °C under oxygen partial pressure gradient.
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000837873 7001_ $$0P:(DE-HGF)0$$aPersoon, E. S.$$b1
000837873 7001_ $$0P:(DE-Juel1)129587$$aBaumann, S.$$b2$$eCorresponding author$$ufzj
000837873 7001_ $$0P:(DE-HGF)0$$aSchroeder, M.$$b3
000837873 7001_ $$0P:(DE-Juel1)129660$$aSchulze-Küppers, F.$$b4$$ufzj
000837873 7001_ $$0P:(DE-HGF)0$$aGörtz, D.$$b5
000837873 7001_ $$0P:(DE-HGF)0$$aBhave, R.$$b6
000837873 7001_ $$0P:(DE-Juel1)129591$$aBram, M.$$b7$$ufzj
000837873 7001_ $$0P:(DE-Juel1)129637$$aMeulenberg, W. A.$$b8$$ufzj
000837873 773__ $$0PERI:(DE-600)1491419-0$$a10.1016/j.memsci.2017.09.011$$gp. S037673881730529X$$p278-286$$tJournal of membrane science$$v544$$x0376-7388$$y2017
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000837873 8564_ $$uhttps://juser.fz-juelich.de/record/837873/files/JMS%20-%20stability%20of%20CGO-FCO_R2.pdf$$yPublished on 2017-09-25. Available in OpenAccess from 2018-09-25.
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