% IMPORTANT: The following is UTF-8 encoded. This means that in the presence % of non-ASCII characters, it will not work with BibTeX 0.99 or older. % Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or % “biber”. @ARTICLE{Mishra:837905, author = {Mishra, S. K. and Mittal, R. and Chaplot, S. L. and Ovsyannikov, S. V. and Trots, D. M. and Dubrovinsky, L. and Su, Y. and Matsuishi, S. and Hosono, H. and Garbarino, G. and Brückel, Thomas}, title = {{P}ressure-driven {P}hase {T}ransition in {C}a{F}e{A}s{F} at 40 and 300 {K}}, journal = {Journal of physics / Conference Series}, volume = {377}, issn = {1742-6596}, address = {Bristol}, publisher = {IOP Publ.}, reportid = {FZJ-2017-06675}, pages = {012034 -}, year = {2012}, abstract = {We carried out systematic investigation of high pressure crystal structure and structural phase transition upto 46 GPa at 40 K and 25 GPa at 300 K in CaFeAsF using powder synchrotron x-ray diffraction experiments. Rietveld analysis of the diffraction data at 40 K reveals a structural phase transition from an orthorhombic to a monoclinic phase at Pc = 13.7 GPa, while increasing pressure. The transition to a lower symmetry phase (orthorhombic to monoclinic) in this 1111 compound under pressure is in contrast with the transition to a high symmetry phase (orthorhombic to tetragonal) as observed in the '122' type compounds. On heating from 40 K at high pressure, CaFeAsF undergoes a monoclinic to tetragonal phase transition around 25 GPa and 200 K. Further, it does not show any post-tetragonal phase transition, as observed in '122' compounds (CaFe2As2, BaFe2As2), and remains in the tetragonal phase upto 25 GPa at 300 K. The dPc/dT slope is found to be positive for CaFeAsF and CaFe2As2, unlike a negative gradient was found in case of BaFe2As2.}, cin = {JCNS-2 / PGI-4 / JARA-FIT / JCNS-FRM-II}, ddc = {530}, cid = {I:(DE-Juel1)JCNS-2-20110106 / I:(DE-Juel1)PGI-4-20110106 / $I:(DE-82)080009_20140620$ / I:(DE-Juel1)JCNS-FRM-II-20110218}, pnm = {144 - Controlling Collective States (POF3-144) / 524 - Controlling Collective States (POF3-524) / 6212 - Quantum Condensed Matter: Magnetism, Superconductivity (POF3-621) / 6213 - Materials and Processes for Energy and Transport Technologies (POF3-621) / 6G4 - Jülich Centre for Neutron Research (JCNS) (POF3-623)}, pid = {G:(DE-HGF)POF3-144 / G:(DE-HGF)POF3-524 / G:(DE-HGF)POF3-6212 / G:(DE-HGF)POF3-6213 / G:(DE-HGF)POF3-6G4}, experiment = {EXP:(DE-MLZ)NOSPEC-20140101}, typ = {PUB:(DE-HGF)16}, UT = {WOS:000307728500034}, doi = {10.1088/1742-6596/377/1/012034}, url = {https://juser.fz-juelich.de/record/837905}, }