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@ARTICLE{Xu:837915,
      author       = {Xu, Junyuan and Wei, Xiankui and Costa, Jose Diogo and
                      Lado, Jose Luis and Owens - Baird, Bryan and Goncalves,
                      Liliana P. L. and Fernandes, Soraia P. S. and Heggen, Marc
                      and Petrovykh, Dmitri Y. and Dunin-Borkowski, Rafal and
                      Kovnir, Kiri and Kolen`ko, Yury V.},
      title        = {{I}nterface {E}ngineering in {N}anostructured {N}ickel
                      {P}hosphide for {E}fficient and {S}table {W}ater
                      {O}xidation},
      journal      = {ACS catalysis},
      volume       = {7},
      number       = {8},
      issn         = {2155-5435},
      address      = {Washington, DC},
      publisher    = {ACS},
      reportid     = {FZJ-2017-06685},
      pages        = {5450 - 5455},
      year         = {2017},
      abstract     = {An approach to significantly enhance the performance of the
                      cost-effective nickel phosphide catalyst for electrochemical
                      water oxidation has been developed via interfacing with Mg
                      oxide-hydroxide. We have synthesized Ni2P nanoparticles
                      anchored on Mg2O(OH)2-like phase supported on carbon paper.
                      During the oxygen evolution reaction, the well-defined Ni2P
                      nanoparticles serve as precursors for the immediate
                      formation of active and stable nanostructured nickel
                      hydroxide catalyst. As the anode for the oxygen evolution
                      reaction in an alkaline electrolyte, the electrode shows a
                      modest Tafel slope of 48 mV dec–1 and a large turnover
                      frequency of 0.05 s–1 at an overpotential of 0.4 V.
                      Microstructure and composition studies of the catalyst
                      suggest that interfacial strain between Mg- and
                      Ni-containing phases is responsible for high catalytic
                      activity. A significant increase in catalytic activity upon
                      the combination of magnesium compound and transition-metal
                      phosphide suggests an interesting strategy for the
                      controlled and reproducible preparation of active
                      Earth-abundant oxygen-evolving catalysts.},
      cin          = {ER-C-1},
      ddc          = {540},
      cid          = {I:(DE-Juel1)ER-C-1-20170209},
      pnm          = {143 - Controlling Configuration-Based Phenomena (POF3-143)},
      pid          = {G:(DE-HGF)POF3-143},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000407309100061},
      doi          = {10.1021/acscatal.7b01954},
      url          = {https://juser.fz-juelich.de/record/837915},
}