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@ARTICLE{Bohn:838135,
author = {Bohn, Birger and Lohse, Insa},
title = {{C}alibration and evaluation of {CCD} spectroradiometers
for ground-based and airborne measurements of spectral
actinic flux densities},
journal = {Atmospheric measurement techniques},
volume = {10},
number = {9},
issn = {1867-8548},
address = {Katlenburg-Lindau},
publisher = {Copernicus},
reportid = {FZJ-2017-06839},
pages = {3151 - 3174},
year = {2017},
abstract = {The properties and performance of charge-coupled device
(CCD) array spectroradiometers for the measurement of
atmospheric spectral actinic flux densities (280–650 nm)
and photolysis frequencies were investigated. These
instruments are widely used in atmospheric research and are
suitable for aircraft applications because of high time
resolutions and high sensitivities in the UV range. The
laboratory characterization included instrument-specific
properties like the wavelength accuracy, dark signal, dark
noise and signal-to-noise ratio (SNR). Spectral
sensitivities were derived from measurements with spectral
irradiance standards. The calibration procedure is described
in detail, and a straightforward method to minimize the
influence of stray light on spectral sensitivities is
introduced. From instrument dark noise, minimum detection
limits
≈ 1 × 1010 cm−2 s−1 nm−1
were derived for spectral actinic flux densities at
wavelengths around 300 nm (1 s integration time). As a
prerequisite for the determination of stray light under
field conditions, atmospheric cutoff wavelengths were
defined using radiative transfer calculations as a function
of the solar zenith angle (SZA) and total ozone column
(TOC). The recommended analysis of field data relies on
these cutoff wavelengths and is also described in detail
taking data from a research flight on HALO (High Altitude
and Long Range Research Aircraft) as an example. An
evaluation of field data was performed by ground-based
comparisons with a double-monochromator-based, highly
sensitive reference spectroradiometer. Spectral actinic flux
densities were compared as well as photolysis frequencies
j(NO2) and j(O1D), representing UV-A and UV-B ranges,
respectively. The spectra expectedly revealed increased
daytime levels of stray-light-induced signals and noise
below atmospheric cutoff wavelengths. The influence of
instrument noise and stray-light-induced noise was found to
be insignificant for j(NO2) and rather limited for j(O1D),
resulting in estimated detection limits of
5 × 10−7 and 1 × 10−7 s−1,
respectively, derived from nighttime measurements on the
ground (0.3 s integration time, 10 s averages). For
j(O1D) the detection limit could be further reduced by
setting spectral actinic flux densities to zero below
atmospheric cutoff wavelengths. The accuracies of photolysis
frequencies were determined from linear regressions with
data from the double-monochromator reference instrument. The
agreement was typically within $±5 \%.$ Because
optical-receiver aspects are not specific for the CCD
spectroradiometers, they were widely excluded in this work
and will be treated in a separate paper, in particular with
regard to airborne applications.},
cin = {IEK-8},
ddc = {550},
cid = {I:(DE-Juel1)IEK-8-20101013},
pnm = {243 - Tropospheric trace substances and their
transformation processes (POF3-243)},
pid = {G:(DE-HGF)POF3-243},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000409039900002},
doi = {10.5194/amt-10-3151-2017},
url = {https://juser.fz-juelich.de/record/838135},
}