Gast ::
| Hauptseite > Publikationsdatenbank > Adsorption-induced symmetry reduction of metal-phthalocyanines studied by vibrational spectroscopy > print |
| Hauptseite > Publikationsdatenbank > Adsorption-induced symmetry reduction of metal-phthalocyanines studied by vibrational spectroscopy > print |
| 001 | 838205 | ||
| 005 | 20230426083152.0 | ||
| 024 | 7 | _ | |a 10.1103/PhysRevB.96.165410 |2 doi |
| 024 | 7 | _ | |a 0163-1829 |2 ISSN |
| 024 | 7 | _ | |a 0556-2805 |2 ISSN |
| 024 | 7 | _ | |a 1094-1622 |2 ISSN |
| 024 | 7 | _ | |a 1095-3795 |2 ISSN |
| 024 | 7 | _ | |a 1098-0121 |2 ISSN |
| 024 | 7 | _ | |a 1550-235X |2 ISSN |
| 024 | 7 | _ | |a 2469-9950 |2 ISSN |
| 024 | 7 | _ | |a 2469-9969 |2 ISSN |
| 024 | 7 | _ | |a 2128/15528 |2 Handle |
| 024 | 7 | _ | |a WOS:000412365700011 |2 WOS |
| 024 | 7 | _ | |a altmetric:12147050 |2 altmetric |
| 037 | _ | _ | |a FZJ-2017-06867 |
| 041 | _ | _ | |a English |
| 082 | _ | _ | |a 530 |
| 100 | 1 | _ | |a Sforzini, Jessica |0 P:(DE-Juel1)157982 |b 0 |
| 245 | _ | _ | |a Adsorption-induced symmetry reduction of metal-phthalocyanines studied by vibrational spectroscopy |
| 260 | _ | _ | |a Woodbury, NY |c 2017 |b Inst. |
| 336 | 7 | _ | |a article |2 DRIVER |
| 336 | 7 | _ | |a Output Types/Journal article |2 DataCite |
| 336 | 7 | _ | |a Journal Article |b journal |m journal |0 PUB:(DE-HGF)16 |s 1670911619_2542 |2 PUB:(DE-HGF) |
| 336 | 7 | _ | |a ARTICLE |2 BibTeX |
| 336 | 7 | _ | |a JOURNAL_ARTICLE |2 ORCID |
| 336 | 7 | _ | |a Journal Article |0 0 |2 EndNote |
| 520 | _ | _ | |a We investigate the vibrational properties of Pt- and Pd-phthalocyanine (PtPc and PdPc) molecules on Ag(111) with high-resolution electron energy loss spectroscopy (HREELS). In the monolayer regime, both molecules exhibit long-range order. The vibrational spectra prove a flat adsorption geometry. The redshift of specific vibrational modes suggests a moderate interaction of the molecules with the substrate. The presence of asymmetric vibrational peaks indicates an interfacial dynamical charge transfer (IDCT). The molecular orbital that is involved in IDCT is the former Eg lowest unoccupied molecular orbital (LUMO) of the molecules that becomes partially occupied upon adsorption. A group-theoretical analysis of the IDCT modes, based on calculated vibrational frequencies and line shape fits, provides proof for the reduction of the symmetry of the molecule-substrate complex from fourfold D4h to C2v(σv), Cs(σv), or C2 and the ensuing lifting of the degeneracy of the former LUMO of the molecule. The vibration-based analysis of orbital degeneracies, as carried out here for PtPc/Ag(111) and PdPc/Ag(111), is particularly useful whenever the presence of multiple molecular in-plane orientations at the interface makes the analysis of orbital degeneracies with angle-resolved photoemission spectroscopy difficult. |
| 536 | _ | _ | |a 523 - Controlling Configuration-Based Phenomena (POF3-523) |0 G:(DE-HGF)POF3-523 |c POF3-523 |f POF III |x 0 |
| 542 | _ | _ | |i 2017-10-05 |2 Crossref |u http://creativecommons.org/licenses/by/3.0/ |
| 588 | _ | _ | |a Dataset connected to CrossRef |
| 700 | 1 | _ | |a Posseik, Francois |0 P:(DE-Juel1)167128 |b 1 |e Corresponding author |u fzj |
| 700 | 1 | _ | |a Tautz, Frank Stefan |0 P:(DE-Juel1)128791 |b 2 |
| 773 | 1 | 8 | |a 10.1103/physrevb.96.165410 |b American Physical Society (APS) |d 2017-10-05 |n 16 |p 165410 |3 journal-article |2 Crossref |t Physical Review B |v 96 |y 2017 |x 2469-9950 |
| 773 | _ | _ | |a 10.1103/PhysRevB.96.165410 |g Vol. 96, no. 16, p. 165410 |0 PERI:(DE-600)2844160-6 |n 16 |p 165410 |t Physical review / B |v 96 |y 2017 |x 2469-9950 |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/838205/files/PhysRevB.96.165410.pdf |y OpenAccess |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/838205/files/PhysRevB.96.165410.gif?subformat=icon |x icon |y OpenAccess |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/838205/files/PhysRevB.96.165410.jpg?subformat=icon-1440 |x icon-1440 |y OpenAccess |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/838205/files/PhysRevB.96.165410.jpg?subformat=icon-180 |x icon-180 |y OpenAccess |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/838205/files/PhysRevB.96.165410.jpg?subformat=icon-640 |x icon-640 |y OpenAccess |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/838205/files/PhysRevB.96.165410.pdf?subformat=pdfa |x pdfa |y OpenAccess |
| 909 | C | O | |o oai:juser.fz-juelich.de:838205 |p openaire |p open_access |p OpenAPC |p driver |p VDB |p openCost |p dnbdelivery |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 1 |6 P:(DE-Juel1)167128 |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 2 |6 P:(DE-Juel1)128791 |
| 913 | 1 | _ | |a DE-HGF |b Key Technologies |l Future Information Technology - Fundamentals, Novel Concepts and Energy Efficiency (FIT) |1 G:(DE-HGF)POF3-520 |0 G:(DE-HGF)POF3-523 |3 G:(DE-HGF)POF3 |2 G:(DE-HGF)POF3-500 |4 G:(DE-HGF)POF |v Controlling Configuration-Based Phenomena |x 0 |
| 914 | 1 | _ | |y 2017 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0200 |2 StatID |b SCOPUS |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0600 |2 StatID |b Ebsco Academic Search |
| 915 | _ | _ | |a JCR |0 StatID:(DE-HGF)0100 |2 StatID |b PHYS REV B : 2015 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0150 |2 StatID |b Web of Science Core Collection |
| 915 | _ | _ | |a WoS |0 StatID:(DE-HGF)0110 |2 StatID |b Science Citation Index |
| 915 | _ | _ | |a WoS |0 StatID:(DE-HGF)0111 |2 StatID |b Science Citation Index Expanded |
| 915 | _ | _ | |a IF < 5 |0 StatID:(DE-HGF)9900 |2 StatID |
| 915 | _ | _ | |a OpenAccess |0 StatID:(DE-HGF)0510 |2 StatID |
| 915 | _ | _ | |a Peer Review |0 StatID:(DE-HGF)0030 |2 StatID |b ASC |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)1150 |2 StatID |b Current Contents - Physical, Chemical and Earth Sciences |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0300 |2 StatID |b Medline |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0199 |2 StatID |b Thomson Reuters Master Journal List |
| 920 | _ | _ | |l yes |
| 920 | 1 | _ | |0 I:(DE-Juel1)PGI-3-20110106 |k PGI-3 |l Quantum Nanoscience |x 0 |
| 980 | _ | _ | |a journal |
| 980 | _ | _ | |a VDB |
| 980 | _ | _ | |a I:(DE-Juel1)PGI-3-20110106 |
| 980 | _ | _ | |a APC |
| 980 | _ | _ | |a UNRESTRICTED |
| 980 | 1 | _ | |a APC |
| 980 | 1 | _ | |a FullTexts |
| 999 | C | 5 | |a 10.1038/16393 |9 -- missing cx lookup -- |2 Crossref |
| 999 | C | 5 | |a 10.1002/adma.200601093 |9 -- missing cx lookup -- |2 Crossref |
| 999 | C | 5 | |a 10.1039/c1cs15047b |9 -- missing cx lookup -- |2 Crossref |
| 999 | C | 5 | |a 10.1016/j.surfrep.2015.04.001 |9 -- missing cx lookup -- |2 Crossref |
| 999 | C | 5 | |a 10.1063/1.121982 |9 -- missing cx lookup -- |2 Crossref |
| 999 | C | 5 | |a 10.1038/35000530 |9 -- missing cx lookup -- |2 Crossref |
| 999 | C | 5 | |a 10.1002/(SICI)1521-4095(199803)10:5%3C365::AID-ADMA365%3E3.0.CO;2-U |9 -- missing cx lookup -- |2 Crossref |
| 999 | C | 5 | |a 10.1021/jp980969y |9 -- missing cx lookup -- |2 Crossref |
| 999 | C | 5 | |a 10.1002/anie.200803305 |9 -- missing cx lookup -- |2 Crossref |
| 999 | C | 5 | |a 10.1103/PhysRevB.78.233409 |9 -- missing cx lookup -- |2 Crossref |
| 999 | C | 5 | |a 10.1016/j.susc.2009.01.029 |9 -- missing cx lookup -- |2 Crossref |
| 999 | C | 5 | |a 10.1021/ja903506s |9 -- missing cx lookup -- |2 Crossref |
| 999 | C | 5 | |a 10.1063/1.3502682 |9 -- missing cx lookup -- |2 Crossref |
| 999 | C | 5 | |a 10.1103/PhysRevB.92.075428 |9 -- missing cx lookup -- |2 Crossref |
| 999 | C | 5 | |a 10.1021/ed045p633 |9 -- missing cx lookup -- |2 Crossref |
| 999 | C | 5 | |a 10.1021/nl304483h |9 -- missing cx lookup -- |2 Crossref |
| 999 | C | 5 | |a 10.1016/j.susc.2013.10.020 |9 -- missing cx lookup -- |2 Crossref |
| 999 | C | 5 | |a 10.1021/jp310196k |9 -- missing cx lookup -- |2 Crossref |
| 999 | C | 5 | |a 10.1098/rspa.1937.0142 |9 -- missing cx lookup -- |2 Crossref |
| 999 | C | 5 | |1 H. Köpper |y 2009 |2 Crossref |t The Jahn-Taller Effect: Fundamentals and Implications for Physics and Chemistry |o H. Köpper The Jahn-Taller Effect: Fundamentals and Implications for Physics and Chemistry 2009 |
| 999 | C | 5 | |a 10.1021/nn5060333 |9 -- missing cx lookup -- |2 Crossref |
| 999 | C | 5 | |a 10.1126/science.1176105 |9 -- missing cx lookup -- |2 Crossref |
| 999 | C | 5 | |a 10.1103/PhysRevB.84.235427 |9 -- missing cx lookup -- |2 Crossref |
| 999 | C | 5 | |a 10.1103/PhysRevB.94.205144 |9 -- missing cx lookup -- |2 Crossref |
| 999 | C | 5 | |1 H. Ibach |y 1982 |2 Crossref |t Electron Energy Loss Spectroscopy and Surface Vibrations |o H. Ibach Electron Energy Loss Spectroscopy and Surface Vibrations 1982 |
| 999 | C | 5 | |1 M. J. Frisch |y 2009 |2 Crossref |t Gaussian09 Revision D.01 |o M. J. Frisch Gaussian09 Revision D.01 2009 |
| 999 | C | 5 | |a 10.1016/j.saa.2006.10.013 |9 -- missing cx lookup -- |2 Crossref |
| 999 | C | 5 | |a 10.1134/S0030400X0612006X |9 -- missing cx lookup -- |2 Crossref |
| 999 | C | 5 | |a 10.1088/1367-2630/12/8/083038 |9 -- missing cx lookup -- |2 Crossref |
| 999 | C | 5 | |a 10.1103/PhysRevB.83.085416 |9 -- missing cx lookup -- |2 Crossref |
| 999 | C | 5 | |a 10.1038/nphys1176 |9 -- missing cx lookup -- |2 Crossref |
| 999 | C | 5 | |1 R. L. Carter |y 1998 |2 Crossref |t Molecular Symmetry and Group Theory |o R. L. Carter Molecular Symmetry and Group Theory 1998 |
| 999 | C | 5 | |a 10.1103/PhysRevB.79.235426 |9 -- missing cx lookup -- |2 Crossref |
| 999 | C | 5 | |a 10.1063/1.3489658 |9 -- missing cx lookup -- |2 Crossref |
| 999 | C | 5 | |a 10.1063/1.3561398 |9 -- missing cx lookup -- |2 Crossref |
| 999 | C | 5 | |a 10.1002/sia.5529 |9 -- missing cx lookup -- |2 Crossref |
| 999 | C | 5 | |a 10.1021/jp409127e |9 -- missing cx lookup -- |2 Crossref |
| 999 | C | 5 | |a 10.1007/978-1-4419-7598-0 |1 R. C. Powell |2 Crossref |9 -- missing cx lookup -- |y 2010 |
| 999 | C | 5 | |a 10.1103/PhysRevLett.55.845 |9 -- missing cx lookup -- |2 Crossref |
| 999 | C | 5 | |a 10.1103/PhysRevB.55.10895 |9 -- missing cx lookup -- |2 Crossref |
| 999 | C | 5 | |a 10.1103/PhysRevB.65.125405 |9 -- missing cx lookup -- |2 Crossref |
| 999 | C | 5 | |a 10.1063/1.3699030 |9 -- missing cx lookup -- |2 Crossref |
| 999 | C | 5 | |a 10.1021/acs.jpclett.6b00299 |9 -- missing cx lookup -- |2 Crossref |
| 999 | C | 5 | |1 F. A. Cotton |y 1990 |2 Crossref |t Chemical Applications of Group Theory |o F. A. Cotton Chemical Applications of Group Theory 1990 |
| 999 | C | 5 | |a 10.1103/PhysRevLett.54.126 |9 -- missing cx lookup -- |2 Crossref |
| 999 | C | 5 | |a 10.1103/PhysRevB.35.4224 |9 -- missing cx lookup -- |2 Crossref |
| 999 | C | 5 | |a 10.1088/0034-4885/69/4/R02 |9 -- missing cx lookup -- |2 Crossref |
| Library | Collection | CLSMajor | CLSMinor | Language | Author |
|---|