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@ARTICLE{Hter:838481,
author = {Hüter, Claas and Fu, Shuo and Finsterbusch, Martin and
Figgemeier, Egbert and Wells, Luke and Spatschek, Robert},
title = {{E}lectrode–{E}lectrolyte {I}nterface {S}tability in
{S}olid {S}tate {E}lectrolyte {S}ystems: {I}nfluence of
{C}oating {T}hickness {U}nder {V}arying {R}esidual
{S}tresses},
journal = {AIMS Materials Science},
volume = {4},
number = {4},
issn = {2372-0484},
address = {Springfield, Mo.},
publisher = {AIMS Press},
reportid = {FZJ-2017-07078},
pages = {867 - 877},
year = {2017},
abstract = {We introduce a model of electrode–electrolyte interfacial
growth which focuses on theeffect of thin coating layers on
the interfacial stability in prestressed systems. We take
into accounttransport resulting from deposition from the
electrolyte, from capillarity driven surface diffusion,
andfrom changes of the chemical potential due to the elastic
energy associated with the interface profile.As model
system, we use metallic lithium as electrode, LLZO as
electrolyte and Al2O3 as a thin filminterlayer, which is a
highly relevant interfacial system in state of the art
all-solid-electrolyte batteries.We consider the stability of
the electrode-coating-electrolyte interface depending on the
thickness ofthe thin film interlayer and the magnitude of
the elastic prestresses. Our central approach is a
linearstability analysis based on the mass conservation at
the planar interface, employing approximationswhich are
appropriate for solid state electrolytes (SSEs) like LLZ, a
thin Li metal electrode and a thincoating layer with a
thickness in the range of nanometres.},
cin = {IEK-1 / IEK-2 / IEK-12 / JARA-HPC},
ddc = {530},
cid = {I:(DE-Juel1)IEK-1-20101013 / I:(DE-Juel1)IEK-2-20101013 /
I:(DE-Juel1)IEK-12-20141217 / $I:(DE-82)080012_20140620$},
pnm = {111 - Efficient and Flexible Power Plants (POF3-111) /
HITEC - Helmholtz Interdisciplinary Doctoral Training in
Energy and Climate Research (HITEC) (HITEC-20170406) /
Battery Failure - Interfacial Stability and non-diagonal
phase field models $(jiek2c_20171101)$},
pid = {G:(DE-HGF)POF3-111 / G:(DE-Juel1)HITEC-20170406 /
$G:(DE-Juel1)jiek2c_20171101$},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000416071000004},
doi = {10.3934/matersci.2017.4.867},
url = {https://juser.fz-juelich.de/record/838481},
}