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@ARTICLE{Drissi:838608,
author = {Drissi, L. B. and Ramadan, F. Z. and Lounis, S.},
title = {{H}alogenation of {S}i{C} for band-gap engineering and
excitonic functionalization},
journal = {Journal of physics / Condensed matter},
volume = {29},
number = {45},
issn = {1361-648X},
address = {Bristol},
publisher = {IOP Publ.},
reportid = {FZJ-2017-07185},
pages = {455001},
year = {2017},
abstract = {The optical excitation spectra and excitonic resonances are
investigated in systematically functionalized SiC with
Fluorine and/or Chlorine utilizing density functional theory
in combination with many-body perturbation theory. The
latter is required for a realistic description of the energy
band-gaps as well as for the theoretical realization of
excitons. Structural, electronic and optical properties are
scrutinized and show the high stability of the predicted
two-dimensional materials. Their realization in laboratory
is thus possible. Large band-gaps of the order of 4 eV are
found in the so-called GW approximation, with the occurrence
of bright excitons, optically active in the four
investigated materials. Their binding energies vary from
0.9 eV to 1.75 eV depending on the decoration choice and
in one case, a dark exciton is foreseen to exist in the
fully chlorinated SiC. The wide variety of opto-electronic
properties suggest halogenated SiC as interesting materials
with potential not only for solar cell applications,
anti-reflection coatings or high-reflective systems but also
for a possible realization of excitonic Bose–Einstein
condensation.},
cin = {IAS-1 / PGI-1 / JARA-FIT / JARA-HPC},
ddc = {530},
cid = {I:(DE-Juel1)IAS-1-20090406 / I:(DE-Juel1)PGI-1-20110106 /
$I:(DE-82)080009_20140620$ / $I:(DE-82)080012_20140620$},
pnm = {142 - Controlling Spin-Based Phenomena (POF3-142)},
pid = {G:(DE-HGF)POF3-142},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:28891810},
UT = {WOS:000425260900001},
doi = {10.1088/1361-648X/aa8b99},
url = {https://juser.fz-juelich.de/record/838608},
}