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@ARTICLE{Warner:838679,
      author       = {Warner, Ben and Gill, Tobias G. and Caciuc, Vasile and
                      Atodiresei, Nicolae and Fleurence, Antoine and Yoshida,
                      Yasuo and Hasegawa, Yukio and Blügel, Stefan and
                      Yamada-Takamura, Yukiko and Hirjibehedin, Cyrus F.},
      title        = {{G}uided {M}olecular {A}ssembly on a {L}ocally {R}eactive
                      2{D} {M}aterial},
      journal      = {Advanced materials},
      volume       = {29},
      number       = {43},
      issn         = {0935-9648},
      address      = {Weinheim},
      publisher    = {Wiley-VCH},
      reportid     = {FZJ-2017-07245},
      pages        = {1703929},
      year         = {2017},
      abstract     = {Atomically precise engineering of the position of molecular
                      adsorbates on surfaces of 2D materials is key to their
                      development in applications ranging from catalysis to
                      single-molecule spintronics. Here, stable room-temperature
                      templating of individual molecules with localized electronic
                      states on the surface of a locally reactive 2D material,
                      silicene grown on ZrB2, is demonstrated. Using a combination
                      of scanning tunneling microscopy and density functional
                      theory, it is shown that the binding of iron phthalocyanine
                      (FePc) molecules is mediated via the strong chemisorption of
                      the central Fe atom to the sp3-like dangling bond of Si
                      atoms in the linear silicene domain boundaries. Since the
                      planar Pc ligand couples to the Fe atom mostly through the
                      in-plane d orbitals, localized electronic states resembling
                      those of the free molecule can be resolved. Furthermore,
                      rotation of the molecule is restrained because of charge
                      rearrangement induced by the bonding. These results
                      highlight how nanoscale changes can induce reactivity in 2D
                      materials, which can provide unique surface interactions for
                      enabling novel forms of guided molecular assembly.},
      cin          = {IAS-1 / PGI-1 / JARA-FIT / JARA-HPC},
      ddc          = {540},
      cid          = {I:(DE-Juel1)IAS-1-20090406 / I:(DE-Juel1)PGI-1-20110106 /
                      $I:(DE-82)080009_20140620$ / $I:(DE-82)080012_20140620$},
      pnm          = {142 - Controlling Spin-Based Phenomena (POF3-142) / 143 -
                      Controlling Configuration-Based Phenomena (POF3-143)},
      pid          = {G:(DE-HGF)POF3-142 / G:(DE-HGF)POF3-143},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000415142100023},
      pubmed       = {pmid:29024122},
      doi          = {10.1002/adma.201703929},
      url          = {https://juser.fz-juelich.de/record/838679},
}