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@ARTICLE{Delisavva:838857,
author = {Delisavva, Foteini and Uchman, Mariusz and Štěpánek,
Miroslav and Kereïche, Sami and Hordyjewicz-Baran, Zofia
and Appavou, Marie-Sousai and Procházka, Karel},
title = {{C}oassembly of {G}emini {S}urfactants with {D}ouble
{H}ydrophilic {B}lock {P}olyelectrolytes {L}eading to
{C}omplex {N}anoassemblies},
journal = {Macromolecules},
volume = {50},
number = {21},
issn = {1520-5835},
address = {Washington, DC},
publisher = {Soc.},
reportid = {FZJ-2017-07367},
pages = {8745-8754},
year = {2017},
abstract = {The electrostatic coassembly of a double hydrophilic block
copolymer poly(2-vinylpyridine)-block-poly(ethylene oxide)
(P2VP–PEO) with the gemini surfactant
6,6′-(ethane-1,2-diylbis(oxy))bis(sodium 3-dodecyl
benzenesulfonate) (G2) was studied in acidic aqueous
solutions by a combination of light scattering, SANS,
Cryo-TEM, and ITC. As the critical micelle concentration of
gemini surfactants is ∼102 times lower than that of
analogous single-tail surfactants, polyelectrolyte chains
interact with G2 vesicles instead of individual G2
molecules. The study shows that hydrophobicity, bulkiness,
and stiffness of G2 domains formed upon its binding to the
P2VP chain affect the coassembly and formation of
nanoparticles. The study allows for presentation of a
comprehensive outline of the coassembling process and
elucidating the structure of the formed nanoparticles.},
cin = {JCNS (München) ; Jülich Centre for Neutron Science JCNS
(München) ; JCNS-FRM-II / Neutronenstreuung ; JCNS-1},
ddc = {540},
cid = {I:(DE-Juel1)JCNS-FRM-II-20110218 /
I:(DE-Juel1)JCNS-1-20110106},
pnm = {6G15 - FRM II / MLZ (POF3-6G15) / 6G4 - Jülich Centre for
Neutron Research (JCNS) (POF3-623)},
pid = {G:(DE-HGF)POF3-6G15 / G:(DE-HGF)POF3-6G4},
experiment = {EXP:(DE-MLZ)KWS2-20140101},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000415911100048},
doi = {10.1021/acs.macromol.7b01330},
url = {https://juser.fz-juelich.de/record/838857},
}